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Alkynes
Known as:
alkyne
, Acetylenes
, Alkynes [Chemical/Ingredient]
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Hydrocarbons with at least one triple bond in the linear portion, of the general formula Cn-H2n-2.
National Institutes of Health
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Related topics
Related topics
48 relations
Narrower (43)
1,3-diformyl-5-ethynylbenzene
1,5-diamino-2-pentyne
1-ethynylcyclohexene
2-hexadecynoic acid
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In Blood
agonists
antagonists & inhibitors
chemical synthesis
Broader (1)
aliphatic hydrocarbons
Papers overview
Semantic Scholar uses AI to extract papers important to this topic.
Review
2011
Review
2011
Gold α-oxo carbenoids in catalysis: catalytic oxygen-atom transfer to alkynes.
Jian Xiao
,
Xingwei Li
Angewandte Chemie
2011
Corpus ID: 24042004
An overview of reactive gold α-oxo carbenoid intermediates in the gold-catalyzed functionalization of alkynes is presented. Such…
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Highly Cited
2010
Highly Cited
2010
Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation.
T. Hyster
,
T. Rovis
Journal of the American Chemical Society
2010
Corpus ID: 207053365
The oxidative cycloaddition of benzamides and alkynes has been developed. The reaction utilizes Rh(III) catalysts in the presence…
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Review
2010
Review
2010
Metal chelating systems synthesized using the copper(I) catalyzed azide-alkyne cycloaddition.
H. Struthers
,
T. Mindt
,
R. Schibli
Dalton Transactions
2010
Corpus ID: 27452604
The copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) is the premier example of a click reaction. The reaction is modular…
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Review
2010
Review
2010
Tricks with clicks: modification of peptidomimetic oligomers via copper-catalyzed azide-alkyne [3 + 2] cycloaddition.
J. Holub
,
K. Kirshenbaum
Chemical Society Reviews
2010
Corpus ID: 205726091
This tutorial review examines recent developments involving use of Copper-catalyzed Azide-Alkyne [3 + 2] Cycloaddition (CuAAC…
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Highly Cited
2009
Highly Cited
2009
Fully Relativistic, Comparative Investigation of Gold and Platinum Alkyne Complexes of Relevance for the Catalysis of Nucleophilic Additions to Alkynes.
M. Pernpointner
,
A. Hashmi
Journal of Chemical Theory and Computation
2009
Corpus ID: 30007363
For a range of additions to alkynes gold is known to exhibit a much higher catalytic activity than a corresponding platinum…
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Highly Cited
2007
Highly Cited
2007
An efficient waste-free oxidative coupling via regioselective C-H bond cleavage: Rh/Cu-catalyzed reaction of benzoic acids with alkynes and acrylates under air.
K. Ueura
,
T. Satoh
,
M. Miura
Organic Letters
2007
Corpus ID: 28524745
[structure: see text]. The direct oxidative coupling of benzoic acids with internal alkynes proceeds efficiently in the presence…
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Review
2007
Review
2007
Heterocycle synthesis by copper facilitated addition of heteroatoms to alkenes, alkynes and arenes.
S. Chemler
,
P. Fuller
Chemical Society Reviews
2007
Corpus ID: 23129212
The de novo synthesis of small organic heterocyclic molecules has benefited from recent protocols for copper-facilitated…
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Highly Cited
2005
Highly Cited
2005
Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.
B. Trost
,
Z. T. Ball
Journal of the American Chemical Society
2005
Corpus ID: 24055192
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access…
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Highly Cited
2003
Highly Cited
2003
Multivalent neoglycoconjugates by regiospecific cycloaddition of alkynes and azides using organic-soluble copper catalysts.
F. Perez-Balderas
,
M. Ortega-Muñoz
,
+5 authors
F. Santoyo-González
Organic Letters
2003
Corpus ID: 20951914
[reaction: see text] The construction of multivalent neoglycoconjugates is efficiently achieved by the regiospecific catalytic…
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Highly Cited
1990
Highly Cited
1990
Palladium- and molybdenum-catalyzed hydrostannation of alkynes: a novel access to regio- and stereodefined vinylstannanes
H. X. Zhang
,
F. Guibé
,
G. Balavoine
1990
Corpus ID: 51684088
In the presence of catalytic amounts of dichlorobis (triphenylphosphine) palladium or of the π-allylmolybdenum complex 3…
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