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An infinite chiral single-helical structure formed in Cu(II)-l-/d-glutamic acid system
Abstract Reaction of Cu(ClO4)2·6H2O with l -glutamic acid ( l -glu) in 1:1 or 1:2 molar ratio at pH 5 gave only the complex [Cu( l -glu)-(H2O)]·H2O, whose crystal structure revealed that the copperExpand
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Supported silver nanoparticle catalyst for selective hydration of nitriles to amides in water.
Hydroxyapatite-supported silver nanoparticles (AgHAP) acted as a highly efficient reusable heterogeneous catalyst for hydration of diverse nitriles, including heteroaromatic ones, into amides inExpand
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One-step Synthesis of Core-Gold/Shell-Ceria Nanomaterial and Its Catalysis for Highly Selective Semihydrogenation of Alkynes.
We report a facile synthesis of new core-Au/shell-CeO2 nanoparticles (Au@CeO2) using a redox-coprecipitation method, where the Au nanoparticles and the nanoporous shell of CeO2 are simultaneouslyExpand
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Efficient Aerobic Oxidation of Alcohols using a Hydrotalcite-Supported Gold Nanoparticle Catalyst
Hydrotalcite-supported gold nanoparticles (Au/HT) were found to be a highly efficient heterogeneous catalyst for the aerobic oxidation of alcohols under mild reaction conditions (40°C, in air). ThisExpand
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Selective deoxygenation of epoxides to alkenes with molecular hydrogen using a hydrotalcite-supported gold catalyst: a concerted effect between gold nanoparticles and basic sites on a support.
Direct conversion of epoxides into the corresponding alkenes is an important reaction because it allows the use of oxirane rings as protecting groups for carbon–carbon double bonds. ThisExpand
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Highly selective hydrogenolysis of glycerol to 1,3-propanediol over a boehmite-supported platinum/tungsten catalyst.
Highly Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over a Boehmite-Supported Platinum/ Tungsten Catalyst Business is boehming: Boehmite-supported platinum nanoparticles and tungstenExpand
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Synthesis and Structure of a New Tripodal Polypyridine Copper(II) Complex That Enables to Recognize a Small Molecule
With a view to constructing an artificial metalloenzyme model complex which can recognize and capture a small molecule, a new tripodal ligand, tris(6-pivaloylamino-2-pyridylmethyl)amine, and itsExpand
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Syntheses, structures, and properties of tetrakis(mu-acetato)dirhodium(II) complexes with axial pyridine nitrogen donor ligands with or without assistance of hydrogen bonds.
Eight adducts of Rh2(O2CCH3)4 with axial pyridine derivatives that contain hydrogen-bonding amino and/or steric methyl substituents in the 2- and 6-positions have been prepared and examined byExpand
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Crystal structure and redox behavior of a novel siderophore model system: a trihydroxamato-iron(III) complex with intra- and interstrand hydrogen bonding networks.
An iron(III) complex of a novel tripodal tris-hydroxamate, tris[2-{(N-acetyl-N-hydroxy)glycylamino}ethyl]amine (TAGE), was synthesized as a siderophore model. Its X-ray structure revealed that intra-Expand
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