norcarane

The heme-thiolate peroxygenase from Agrocybe aegerita (AaeAPO, EC 1.11.2.1) is a versatile biocatalyst and cytochrome P450… (More)

Fungal peroxygenases are novel extracellular heme-thiolate biocatalysts that are capable of catalyzing the selective… (More)

Mechanistically informative chemical probes are used to characterize the activity of functional alkane hydroxylases in whole… (More)

Norcarane, bicyclo[4.1.0]heptane, has been widely used as a mechanistic probe in studies of oxidations catalyzed by several iron… (More)

Whole cells expressing the non-heme diiron hydroxylases AlkB and toluene 4-monooxygenase (T4MO) were used to probe enzyme… (More)

Toluene 4-monooxygenase (T4MO) catalyzes the hydroxylation of toluene to yield 96% p-cresol. This diiron enzyme complex was used… (More)

Ozonation of norcarane (1) yielded endo and exo norcarane hydrotrioxides (2a, 2b), as characterized by (1)H and (13)C NMR… (More)

Norcarane (1) and spiro[2.5]octane (2) yield different product distributions depending on whether they are oxidized via concerted… (More)

Norcarane was employed as a mechanistic probe in oxidations catalyzed by hepatic cytochome P450 enzymes and by the soluble… (More)

Norcarane is a valuable mechanistic probe for enzyme-catalyzed hydrocarbon oxidation reactions because different products or… (More)