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norcarane

National Institutes of Health

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Terpenes

Papers overview

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2016
2016
Mechanistic Investigation And Potential Application Of A Fatty Acid Decarboxylating Cytochrome P450 Peroxygenase
ion occurred at Cβ position. 1.3 Non-heme diiron enzymes Cyanobacterial aldehyde decarbonylase (cADO) was the first family of non… 
2013
2013
Identity and mechanisms of alkane-oxidizing metalloenzymes from deep-sea hydrothermal vents
Six aerobic alkanotrophs (organism that can metabolize alkanes as their sole carbon source) isolated from deep-sea hydrothermal… 
2009
2009
The effect of a complexed lithium cation on a norcarane-based radical clock.
Density-functional theory (DFT) and ab initio calculations have been used to investigate the effect of a complexed lithium cation… 
2007
2007
Desaturase reactions complicate the use of norcarane as a mechanistic probe. Unraveling the mixture of twenty-plus products formed in enzyme-catalyzed oxidations of norcarane.
Norcarane, bicyclo[4.1.0]heptane, has been widely used as a mechanistic probe in studies of oxidations catalyzed by several iron… 
2007
2007
Products from enzyme-catalyzed oxidations of norcarenes.
Recent studies revealed that norcarane (bicyclo[4.1.0]heptane) is oxidized to 2-norcarene (bicyclo[4.1.0]-hept-2-ene) and 3… 
Review
2005
Review
2005
Oxygen-18 tracer studies of enzyme reactions with radical/cation diagnostic probes.
2004
2004
Remarkable aliphatic hydroxylation by the diiron enzyme toluene 4-monooxygenase in reactions with radical or cation diagnostic probes norcarane, 1,1-dimethylcyclopropane, and 1,1-diethylcyclopropane.
Toluene 4-monooxygenase (T4MO) catalyzes the hydroxylation of toluene to yield 96% p-cresol. This diiron enzyme complex was used… 
2003
2003
endo/exo isomerism in norcarane and 2-norcaranol hydrotrioxides (ROOOH).
Ozonation of norcarane (1) yielded endo and exo norcarane hydrotrioxides (2a, 2b), as characterized by (1)H and (13)C NMR… 
Highly Cited
2002
Highly Cited
2002
Evaluation of norcarane as a probe for radicals in cytochome p450- and soluble methane monooxygenase-catalyzed hydroxylation reactions.
Norcarane was employed as a mechanistic probe in oxidations catalyzed by hepatic cytochome P450 enzymes and by the soluble… 
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