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trimethylsilyl cyanide

Known as: TMSCN 
National Institutes of Health

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2 relations

Broader (2)

CyanidesTrimethylsilyl Compounds

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2017
2017
Access to Cyano-Containing Isoxazolines via Copper-Catalyzed Domino Cyclization/Cyanation of Alkenyl Oximes.
A highly efficient copper-catalyzed cyclization/cyanation cascade of unactivated olefins bearing oximes is described. A variety… 
2016
2016
Iron-catalysed sequential reaction towards α-aminonitriles from secondary amines, primary alcohols and trimethylsilyl cyanide.
We have developed a one-pot iron-catalysed sequential reaction of secondary amines with primary alcohols, trimethylsilyl cyanide… 
2014
2014
Oxidative nucleophilic strategy for synthesis of thiocyanates and trifluoromethyl sulfides from thiols.
Thiocyanates and trifluoromethyl sulfides are important compounds and have classically been synthesized via multistep procedures… 
Highly Cited
2009
Highly Cited
2009
An expeditious synthesis of cyanohydrin trimethylsilyl ethers using tetraethylammonium 2-(carbamoyl)benzoate as a bifunctional organocatalyst
Highly Cited
2008
Highly Cited
2008
Asymmetric three-component Strecker reactions catalyzed by trans-4-hydroxy-L-proline-derived N,N'-dioxides.
Novel trans-4-hydroxy-L-proline-derived N,N'-dioxides have been developed and used as efficient organocatalysts for the one-pot… 
2007
2007
Exceptionally active yttrium-salen complexes for the catalyzed ring opening of epoxides by TMSCN and TMSN(3).
Halide or alkoxide free yttrium-salen complexes are excellent catalysts for the ring opening of epoxides mediated by TMSCN and… 
Highly Cited
2006
Highly Cited
2006
Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds.
N-Heterocyclic carbenes were found to be highly effective organocatalysts in activating TMSCN for facile cyanosilylation of… 
2004
2004
Achiral phenolic N-oxides as additives: an alternative strategy for asymmetric cyanosilylation of ketones
Highly Cited
2000
Highly Cited
2000
Ring-opening of N-tosylaziridines with TMSN^3 and TMSCN Triggered by TBAF: An efficient and convenient route to vicinal diamines and β=aminoacid
Ring-opening reactions of aziridines with trimethylsilyl compounds triggered by tetrabutylammonium fluoride give the… 
Highly Cited
1998
Highly Cited
1998
Diastereo- and Enantioselective Alkylation of alpha-Imino Esters with Enol Silanes Catalyzed by (R)-Tol-BINAP-CuClO(4).(MeCN)(2).
The past few years have witnessed a profusion of highly efficient, catalytic, enantioand diastereoselective alkylations of… 
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