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trimethylsilyl cyanide

Known as: TMSCN 
National Institutes of Health

Related topics

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2 relations

Broader (2)

CyanidesTrimethylsilyl Compounds

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2020
2020
Carbonyl-stabilized Phosphorus Ylide as Organocatalyst for Cyanosilylation Reaction Using TMSCN.
We report carbonyl-stabilized phosphorus ylides as general and efficient catalysts for the cyanosilylation of ketones. The N,N… 
2017
2017
Access to Cyano-Containing Isoxazolines via Copper-Catalyzed Domino Cyclization/Cyanation of Alkenyl Oximes.
A highly efficient copper-catalyzed cyclization/cyanation cascade of unactivated olefins bearing oximes is described. A variety… 
2016
2016
Iron-catalysed sequential reaction towards α-aminonitriles from secondary amines, primary alcohols and trimethylsilyl cyanide.
We have developed a one-pot iron-catalysed sequential reaction of secondary amines with primary alcohols, trimethylsilyl cyanide… 
2014
2014
Oxidative nucleophilic strategy for synthesis of thiocyanates and trifluoromethyl sulfides from thiols.
Thiocyanates and trifluoromethyl sulfides are important compounds and have classically been synthesized via multistep procedures… 
2012
2012
The intramolecular allenolate Rauhut-Currier reaction.
An intramolecular Rauhut-Currier reaction utilizing alkynoates as the initial conjugate acceptor affords densely functionalized 5… 
2010
2010
Catalytic dicyanative [4 + 2] cycloaddition triggered by cyanopalladation using ene-enynes and cyclic enynes with methyl acrylate.
Palladium-catalyzed dicyanative [4 + 2] cycloaddition using various ene-enynes was investigated. The key species in this process… 
Highly Cited
2009
Highly Cited
2009
An expeditious synthesis of cyanohydrin trimethylsilyl ethers using tetraethylammonium 2-(carbamoyl)benzoate as a bifunctional organocatalyst
Highly Cited
2008
Highly Cited
2008
Asymmetric three-component Strecker reactions catalyzed by trans-4-hydroxy-L-proline-derived N,N'-dioxides.
Novel trans-4-hydroxy-L-proline-derived N,N'-dioxides have been developed and used as efficient organocatalysts for the one-pot… 
2007
2007
Exceptionally active yttrium-salen complexes for the catalyzed ring opening of epoxides by TMSCN and TMSN(3).
Halide or alkoxide free yttrium-salen complexes are excellent catalysts for the ring opening of epoxides mediated by TMSCN and… 
2004
2004
Achiral phenolic N-oxides as additives: an alternative strategy for asymmetric cyanosilylation of ketones
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