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trimethylsilyl cyanide

Known as: TMSCN 
National Institutes of Health

Papers overview

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Highly Cited
2011
Highly Cited
2011
New phase transfer catalysts are reported for the first example of an organocatalytic asymmetric conjugate addition of cyanide… Expand
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Highly Cited
2011
Highly Cited
2011
We report a new thiourea-Brønsted acid cooperative catalytic system for the enantioselective cyanosilylation of aldehydes with… Expand
Highly Cited
2009
Highly Cited
2009
An aluminum complex was found to be high yielding and enantioselective for the addition of cyanide to aldimines and ketimines… Expand
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Highly Cited
2009
Highly Cited
2009
using a variety ofnucleophiles have been the subject of extensive research. Theless developed ring-opening reactions, those of… Expand
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Highly Cited
2009
Highly Cited
2009
Panacea for aldol desymmetrizations: We describe an easy entry for the desymmetrization of 4-substituted-cyclohexanones catalyzed… Expand
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Highly Cited
2007
Highly Cited
2007
Hypervalent iodine(III) reagents mediate the direct cyanating reaction of a wide range of electron-rich heteroaromatic compounds… Expand
Highly Cited
2006
Highly Cited
2006
N-Heterocyclic carbenes were found to be highly effective organocatalysts in activating TMSCN for facile cyanosilylation of… Expand
Highly Cited
2005
Highly Cited
2005
A catalytic enantioselective desymmetrization of meso-N-p-nitrobenzoylaziridines with TMSCN was developed using a chiral… Expand
Highly Cited
2004
Highly Cited
2004
The first catalytic enantioselective Reissert reaction of pyridine derivatives that affords products with excellent regio- and… Expand
Highly Cited
1998
Highly Cited
1998
The past few years have witnessed a profusion of highly efficient, catalytic, enantioand diastereoselective alkylations of… Expand
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