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trimethylsilyl cyanide

Known as: TMSCN 
National Institutes of Health

Papers overview

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Review
2012
Review
2012
Aromatic nitriles are prepared efficiently through transition-metal-mediated cyanation of aryl (pseudo)halides with metallic… 
Highly Cited
2011
Highly Cited
2011
New phase transfer catalysts are reported for the first example of an organocatalytic asymmetric conjugate addition of cyanide… 
Highly Cited
2009
Highly Cited
2009
using a variety ofnucleophiles have been the subject of extensive research. Theless developed ring-opening reactions, those of… 
Highly Cited
2007
Highly Cited
2007
Hypervalent iodine(III) reagents mediate the direct cyanating reaction of a wide range of electron-rich heteroaromatic compounds… 
Highly Cited
2006
Highly Cited
2006
N-Heterocyclic carbenes were found to be highly effective organocatalysts in activating TMSCN for facile cyanosilylation of… 
Highly Cited
2005
Highly Cited
2005
A catalytic enantioselective desymmetrization of meso-N-p-nitrobenzoylaziridines with TMSCN was developed using a chiral… 
Highly Cited
2004
Highly Cited
2004
The first catalytic enantioselective Reissert reaction of pyridine derivatives that affords products with excellent regio- and… 
Highly Cited
2004
Highly Cited
2004
Double-activation catalysis promises high catalytic efficiency in the enantioselective cyanosilylation of ketones through the… 
Review
2001
Review
2001
Two types of general and practical enantioselective catalysts, namely, bimetallic complexes and Lewis acid-Lewis base… 
Highly Cited
1998
Highly Cited
1998
The past few years have witnessed a profusion of highly efficient, catalytic, enantioand diastereoselective alkylations of…