C. Senanayake

Publications545
h-index53
Citations10,255
Highly Influential Citations36
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Rapid access to enantiopure bupropion and its major metabolite by stereospecific nucleophilic substitution on an α-ketotriflate
Overcoming barriers to green chemistry in the pharmaceutical industry – the Green Aspiration Level™ concept
“Green chemistry” refers to the promotion of safe, sustainable, and waste-minimizing chemical processes. The proliferation of green chemistry metrics without any clear consensus on industry standards…
Mechanistic studies on the chiral recognition of polysaccharide-based chiral stationary phases using liquid chromatography and vibrational circular dichroism: reversal of elution order of…
A superior method for the reduction of secondary phosphine oxides.
TLDR
DIBAL-H and triisobutylaluminum hydride have been found to be outstanding reductants for secondary phosphine oxides (SPOs), and many SPOs can now be reduced at cryogenic temperatures, and conditions for preservation of reducible functional groups have be found.
An improved method of amide synthesis using acyl chlorides
Organometallic methods for the synthesis and functionalization of azaindoles.
TLDR
In this tutorial review, a survey of the recent development of organometallic chemistry-based methods for azaindole synthesis is surveyed.
Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds.
TLDR
N-Heterocyclic carbenes were found to be highly effective organocatalysts in activating TMSCN for facile cyanosilylation of carbonyl compounds and tolerate various functional groups.
Chromatographic and spectroscopic studies on the chiral recognition of sulfated beta-cyclodextrin as chiral mobile phase additive enantiomeric separation of a chiral amine.
Chiral mandelic acid template provides a highly practical solution for (S)-oxybutynin synthesis.
Vibrational circular dichroism of amylose carbamate: structure and solvent-induced conformational changes
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