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General and efficient route for the synthesis of 3,4-disubstituted coumarins via Pd-catalyzed site-selective cross-coupling reactions.
Palladium-catalyzed site-selective cross-coupling reactions of 3-bromo-4-trifloxycoumarin or 3-bromo-4-tosyloxycoumarin provide an efficient and facile route for the synthesis of 3,4-disubstitutedExpand
Synthesis of highly functionalized polycyclic quinoxaline derivatives using visible-light photoredox catalysis.
TLDR
A telescoped preparation of these polycyclic compounds by integration of the in-line isocyanide formation and photochemical cyclization has been established in a three-step continuous-flow system. Expand
I2-mediated oxidative C-N bond formation for metal-free one-pot synthesis of di-, tri-, and tetrasubstituted pyrazoles from α,β-unsaturated aldehydes/ketones and hydrazines.
TLDR
An I2-mediated metal-free oxidative C-N bond formation methodology has been established for the regioselective pyrazole synthesis and provides a facile access to a variety of di-, tri-, and tetrasubstituted pyrazoles from readily available α,β-unsaturated aldehydes/ketones and hydrazine salts. Expand
Design, synthesis, and biological evaluation of new 2'-deoxy-2'-fluoro-4'-triazole cytidine nucleosides as potent antiviral agents.
TLDR
Among them, compounds 9, 10 and 13 exhibited extremely potent antiviral activity, thus had a great potential for further development as novel nucleoside reverse transcriptase inhibitors (NRTIs) for the treatment of HIV-1 infection. Expand
Nitrogen-doped porous carbon derived from metal-organic gel for electrochemical analysis of heavy-metal ion.
  • Lin Cui, Jie Wu, H. Ju
  • Materials Science, Medicine
  • ACS applied materials & interfaces
  • 15 September 2014
TLDR
The mesoporous structure, fast electron transfer ability, and simple and green synthesis of N@MOG-C made it a promising electrode material for practical applications in heavy-metal-ion sensing. Expand
Synthesis of 2-amino-1,3,4-oxadiazoles and 2-amino-1,3,4-thiadiazoles via sequential condensation and I2-mediated oxidative C–O/C–S bond formation.
TLDR
This transition-metal-free sequential synthesis process is compatible with aromatic, aliphatic, and cinnamic aldehydes, providing facile access to a variety of diazole derivatives bearing a 2-amino substituent in an efficient and scalable fashion. Expand
Palladium-catalyzed cross-coupling reactions of 4-tosylcoumarin and arylboronic acids: synthesis of 4-arylcoumarin compounds
The palladium-catalyzed reaction between 4-tosylatecoumarin and arylboronic acids was investigated. This reaction provides an efficient approach to synthesize diversified 4-arylcoumarins in goodExpand
Diversity-oriented synthesis of functionalized quinolin-2(1H)-ones via Pd-catalyzed site-selective cross-coupling reactions.
TLDR
The key steps, which introduced selectivity and diversity in the synthesis, were the palladium-catalyzed site-selective Suzuki-Miyaura/Buchwald-Hartwig amination and Suzuki-Roche/Heck coupling reactions of 3-bromo-4-trifloxy-quinolin-2(1H)-one. Expand
Photo-induced thiol coupling and C–H activation using nanocrystalline lead-halide perovskite catalysts
The use of photon energy to promote chemical transformations offers versatile control of reaction kinetics and progress. Over the past decade, many photoactive transition-metal complexes and organicExpand
Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C-H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect.
TLDR
The CuI-CPs performed the reaction with high regioselectivity due to the unique spatial confinement effect of CPs, making the catalytic system fascinating. Expand
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