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ethyl propiolate

 
National Institutes of Health

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2 relations

Broader (2)

AlkynesPropionates

Papers overview

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2017
2017
A Unified Continuous Flow Assembly Line Synthesis of Highly Substituted Pyrazoles and Pyrazolines
A rapid and modular continuous flow synthesis of highly functionalized fluorinated pyrazoles and pyrazolines has been developed… Expand
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Highly Cited
2013
Highly Cited
2013
Organocatalytic, regioselective nucleophilic "click" addition of thiols to propiolic acid esters for polymer-polymer coupling.
The regioselectivity of the nucleophilic addition of thiols to electron-deficient alkynes is controlled by the choice of the… Expand
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Highly Cited
2012
Highly Cited
2012
Thionium ion initiated medium-sized ring formation: the total synthesis of asteriscunolide D.
The first synthesis of the biologically active humulene natural product asteriscunolide D has been accomplished in nine steps… Expand
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2011
2011
Ethyl propiolate as a post-column derivatization reagent for thiols: development of a green liquid chromatographic method for the determination of glutathione in vegetables.
The present study reports the development, validation and application of a new green liquid chromatographic method for the… Expand
2007
2007
Coupling of activated esters to gramines in the presence of ethyl propiolate under mild conditions.
The coupling of activated esters to gramine derivatives is described using ethyl propiolate. A series of substrates have been… Expand
2007
2007
Domino reaction of 3-(2-formylphenoxy)propenoates and amines: a novel synthesis of 1,4-dihydropyridines from salicaldehydes, ethyl propiolate, and amines.
A novel synthesis of Hantzsch-type N-substituted 1,4-dihydropyridines from salicaldehydes, ethyl propiolate, and amines has been… Expand
2005
2005
Stereoselective synthesis of hex-2-(E)-en-4-yn-1,6-dioates and E,Z-muconic acid diesters via organo-catalyzed self-coupling of propiolates
Alkyl propiolate couples with itself in the presence of catalytic DABCO under very mild conditions to provide a quantitative… Expand
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Highly Cited
2004
Highly Cited
2004
Phosphine-mediated reductive condensation of gamma-acyloxy butynoates: a diversity oriented strategy for the construction of substituted furans.
Exposure of gamma-acyloxy butynoates to stoichiometric quantities of triphenylphosphine results in reductive condensation to… Expand
Highly Cited
1996
Highly Cited
1996
Preparation of Functionalized Dialkylzincs via a Boron-Zinc Exchange. Reactivity and Catalytic Asymmetric Addition to Aldehydes.
The hydroboration of olefins with Et(2)BH provides diethyl(alkyl)boranes 2 which readily undergo a boron-zinc exchange with Et(2… Expand
1988
1988
Tumor promoters induce a transient expression of tumor-associated genes in both basal and differentiated cells of the mouse epidermis.
The effect of tumor promoters on the in vivo expression of tumor-associated, overexpressed genes was studied. Two of the tumor… Expand
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