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azaspirene

National Institutes of Health

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2 relations

Broader (2)

PyrrolidinonesSpiro Compounds

Papers overview

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2018
2018
Elucidation of Racemization Process of Azaspirene Skeleton in Neutral Aqueous Media.
Azaspirene and related congeners, which possess various biological activities, have a unique spirocyclic core structure. However… 
2017
2017
Six-Step Total Synthesis of Azaspirene.
The total synthesis of (±)-azaspirene (1) was achieved in a total of six steps from commercially available materials. Keys to the… 
2016
2016
Total Synthesis of Lagunamide A via Remote Vinylogous Mukaiyama Aldol Reactions, Chemical Studies Toward the Total Synthesis of Micromide and Preliminary Studies Toward the Total Synthesis of…
Author(s): Banasik, Brent | Advisor(s): Bergdahl, Mikael; Molinski, Tadeusz | Abstract: Lagunamide A represents a class of novel… 
2016
2016
Straightforward Synthesis of 2(5H)-Furanones as Promising Cross-Coupling Partners: Direct Furanone Annulation Utilizing Ti-Mediated Aldol Addition
Direct 2(5H)-furanone annulation produces promising cross-coupling partners incorporating m- or p-bromo- and p-tosyloxyphenyl… 
2015
2015
Azaspirene analogs inhibit the growth of human uterine carcinosarcoma in vitro and in vivo.
Uterine carcinosarcoma is a highly aggressive gynecological neoplasm that responds poorly to conventional chemotherapy and… 
2014
2014
Progress Toward a Scalable Synthesis of Azaspirene, An Angiogenesis Inhibitor and Synthesis of 2-Amino-benzimidazole Compounds Targeting Subdomain IIa of the Internal Ribosome Entry Site Inhibiting…
Author(s): Schmit, David John | Abstract: Chemical studies toward the synthesis of an angiogenesis inhibitor azaspirene is… 
2009
2009
Towards a Total Synthesis of Azaspirene
2007
2007
Photochemical and thermal reactions of intermediates in the phenylnitrene rearrangement inside a hemicarcerand.
Broadband irradiation (lambda > 320 nm) of hemicarceplex H(.)1 between -74 degrees C and -84 degrees C, produces encapsulated… 
2007
2007
Part I: Copper(I) iodide dimethyl sulfide catalyzed 1,4-addition of alkenyl groups from alkenylzirconium and alkenylzinc reagents and their application toward the total synthesis of azaspirene, and…
Hydrozirconation of alkynes, utilizing Schwartz's reagent, }Cp2Zr(H)Cl}, is a superb protocol for making regioselective… 
Highly Cited
2002
Highly Cited
2002
Azaspirene: a novel angiogenesis inhibitor containing a 1-oxa-7-azaspiro[4.4]non-2-ene-4,6-dione skeleton produced by the fungus Neosartorya sp.
[structure: see text] Azaspirene isolated from the fungus Neosartorya sp. is a novel angiogenesis inhibitor with a 1-oxa-7… 
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