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Oxepins

Known as: Oxepin, Oxepins [Chemical/Ingredient], Oxepenes 
Compounds based on a 7-membered heterocyclic ring including an oxygen. They can be considered a medium ring ether. A natural source is the MONTANOA… 
National Institutes of Health

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2-methylene-1,3-dioxepane3-methyl-4,5-dihydro-oxepineacetylaranotinderquantel
In Bloodagonistsantagonists & inhibitorsaspects of radiation effects

Papers overview

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2019
2019
Concise Seven-Membered Oxepene/Oxepane Synthesis – Structural Motifs in Natural and Synthetic Products
Abstract This work outlines a suitable method for the synthesis of oxepane skeleton using iterative C-glycoside technology on the… 
2018
2018
Iron-Catalyzed Prins-Peterson Reaction for the Direct Synthesis of Δ4-2,7-Disubstituted Oxepenes.
A direct iron(III)-catalyzed Prins-Peterson reaction involving α-substituted γ-triphenylsilyl bis-homoallylic alcohols and… 
2008
2008
Evidence from mechanistic probes for distinct hydroperoxide rearrangement mechanisms in the intradiol and extradiol catechol dioxygenases.
Three mechanistic probes were used to investigate whether the Criegee rearrangement step of catechol 1,2-dioxygenase (CatA) from… 
2005
2005
Synthetic approaches and total synthesis of natural zoapatanol.
[structure: see text] The total synthesis of (+)-zoapatanol utilizing an intramolecular Horner-Wadsworth-Emmons olefination and… 
2005
2005
Reactions of benzene oxide with thiols including glutathione.
S-Phenylmercapturic acid is a minor metabolite of benzene used as a biomarker for human benzene exposures. The reaction of… 
2004
2004
Novel stereocontrolled approach to syn- and anti-oxepene-cyclogeranyl trans-fused polycyclic systems: asymmetric total synthesis of (-)-Aplysistatin, (+)-Palisadin A, (+)-Palisadin B, (+)-12-hydroxy…
A new stereocontrolled method for the formation of trans-anti cyclogeranyl-oxepene systems is described. The demanding… 
Highly Cited
2003
Highly Cited
2003
Intramolecular reactions of alkynes with furans and electron rich arenes catalyzed by PtCl2: the role of platinum carbenes as intermediates.
5-(2-Furyl)-1-alkynes react, with PtCl(2) as catalyst, to give phenols. On the basis of DFT calculations, a cyclopropyl… 
2003
2003
Enantioselective total synthesis of (+)-rogioloxepane A.
[reactiojn: see text] The enantioselective synthesis of (+)-rogioloxepane A has been achieved in 21 steps from 1,5-hexadien-3-ol… 
2001
2001
Non-steroidal and steroidal sulfamates: new drugs for cancer therapy
1988
1988
Oxidative metabolism of the carcinogen 6-fluorobenzo[c]phenanthrene. Effect of a K-region fluoro substituent on the regioselectivity of cytochromes P-450 in liver microsomes from control and induced…
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