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Cephalexin Dihydride

Known as: Dihydride, Cephalexin 
National Institutes of Health

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Cephalexin

Papers overview

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2018
2018
Reductive O2 Binding at a Dihydride Complex Leading to Redox Interconvertible μ-1,2-Peroxo and μ-1,2-Superoxo Dinickel(II) Intermediates.
Dioxygen activation at nickel complexes is much less studied than for the biologically more relevant iron or copper systems but… 
Highly Cited
2016
Highly Cited
2016
Ammonia Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I) Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst.
The pincer d(8)-monohydride complex RhH{xant(P(i)Pr2)2} (xant(P(i)Pr2)2 = 9,9-dimethyl-4,5-bis(diisopropylphosphino)xanthene… 
Highly Cited
2015
Highly Cited
2015
Elementary steps of iron catalysis: exploring the links between iron alkyl and iron olefin complexes for their relevance in C-H activation and C-C bond formation.
The alkylation of complexes 2 and 7 with Grignard reagents containing β-hydrogen atoms is a process of considerable relevance for… 
Highly Cited
2009
Highly Cited
2009
Donor/acceptor stabilization of Ge(II) dihydride.
A combined donor/acceptor approach is presented for the stabilization of the parent germylene, :GeH2. 
2009
2009
Bulky triazenide complexes of alumino- and gallohydrides.
The sterically bulky triazenes DitopN(3)(H)pTol, DitopN(3)(H)Mes, DmpN(3)(H)pTol and DmpN(3)(H)Mes, where Ditop = 2,6-di-p… 
Highly Cited
2007
Highly Cited
2007
Escherichia coli has multiple enzymes that attack TNT and release nitrogen for growth.
There has been a growing interest in the degradation of 2,4,6-trinitrotoluene (TNT) over the last decade, ever since its removal… 
2006
2006
Methane activation by laser-ablated V, Nb, and Ta atoms: Formation of CH3-MH, CH2=MH2, CHMH3-, and (CH3)2MH2.
Methane activation by group 5 transition-metal atoms in excess argon and the matrix infrared spectra of reaction products have… 
Highly Cited
2005
Highly Cited
2005
Mechanistic insights into iridium-catalyzed asymmetric hydrogenation of dienes.
Hydrogenation of 2,3-diphenylbutadiene (1) with the chiral carbene-oxazoline-iridium complex C has been studied by means of a… 
2004
2004
Nucleophilic de-coordination and electrophilic regeneration of "hemilabile" pincer-type complexes: formation of anionic dialkyl, diaryl, and dihydride Pt(II) complexes bearing no stabilizing pi…
Novel anionic dialkyl, diaryl, and dihydride platinum(II) complexes based on the new "long-arm" hemilabile PCN-type ligand C6H4… 
Highly Cited
2004
Highly Cited
2004
A paradigm change in assembling OH functionalities on metal centers.
The synthesis of terminal hydroxide containing Group 13 and 14 metals [LAl(OH)(2)], LAlMeOH, [{LAl(OH)}(2)(mu-O)], LAl(OH)-O-AlLL… 
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