spiroketal
National Institutes of Health
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The convergent synthesis of two pentacyclic analogues of the polyether monensin A is described. Although different with respect…
Abstract A highly efficient approach to the synthesis of spiroketals involves the double cyclization of alkynyl diols using…
[reaction: see text] A convergent synthesis of 14 corresponding to the A-B spiroketal core of spongistatin 1 has been…
The total synthesis of the epidermal growth factor inhibitor reveromycin B (2) in 25 linear steps from chiral methylene pyran 13…
The synthesis of the CD spiroketal fragment of spongistatin 1 (altohyrtin A) has been accomplished utilizing the addition of a…
[structure: see text] Reveromycin A (1) belongs to a family of microbial polyketides with unusual structural features and…
A new member of the spiroketal-containing macrolide class of fermentation-derived natural products was isolated from mycelial…
A novel complex of antifungal and immunosuppressant compounds has been isolated from the fermentation broth and mycelia of two…