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pentalenene

Known as: (1 alpha,3a alpha,5a beta,8aR*)-1,2,3,3a,5a,6,7,8-octahydro-1,4,7,7-tetramethylcyclopenta(c)pentalene 
National Institutes of Health

Related topics

Related topics

1 relation

Broader (1)

Cyclopentanes

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2016
2016
Exploring the diversification mechanism of skeletal construction in representative natural product families
Exploring the diversification mechanism of skeletal construction in representative natural product families 
2015
2015
Trimethylenemethane diyl mediated tandem cycloaddition reactions: mechanism based design of synthetic strategies.
Several criteria for the measure of synthetic strategies toward "ideal synthesis" are available to guide the design and… 
2014
2014
Pentalenene formation mechanisms redux.
Quantum chemical calculations are used to assess various means of lowering the barrier for the dyotropic rearrangement previously… 
Review
2009
Review
2009
[Overview of 40 years' chemical study].
  • T. Imanishi
  • Yakugaku zasshi : Journal of the Pharmaceutical…
  • 2009
  • Corpus ID: 25279080
1,6-Dihydro-3(2H)-pyridinone, designed as a common synthon for synthesis of various natural products, was found to be easily… 
2003
2003
π4s+π2s Cycloaddition between electron deficient π-systems and photoreaction of β,γ-enones: a novel stereoselective entry into angular triquinanes
2002
2002
A highly abbreviated synthesis of pentalenene by means of the squarate ester cascade.
[reaction: see text] The sequential addition of 5-methylcyclopentyllithium and propynyllithium to diisopropyl squarate results in… 
1995
1995
Crystallization and preliminary X‐ray diffraction analysis of recombinant pentalenene synthase
Recombinant pentalenene synthase, a 42.5‐kDa sesquiterpene cyclase originally isolated from Streptomyces UC5319 and cloned in… 
1991
1991
Terpenoid biosynthesis and the stereochemistry of enzyme-catalysed allylic addition-elimination reactions.
Allylic addition-elimination reactions are widely used in the enzyme-catalysed formation of terpenoid metabolites. It has earlier… 
1987
1987
Partial purification and characterization of pentalenene synthase.
1986
1986
Regulation of enzymes involved in the biosynthesis of the sesquiterpene antibiotic pentalenolactone in Streptomyces arenae.
The production of the sesquiterpenoid antibiotic pentalenolactone in the producer strain Streptomyces arenae TU 469 is controlled… 
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