nitrene
National Institutes of Health
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Stereoselective catalytic intermolecular C-H amination of complex molecules is reported. Site-selective functionalizations occur…
The metastable iron(III) imido species LtBuFeNAd catalyzes transfer of the nitrene fragment NAd from an organic azide to…
Simple AuCl3 can mediate direct nitrene insertion into aromatic and benzylic C−H groups at room temperature.
A simple copper-based catalytic system has been developed for the carbon-hydrogen amidation reaction. The copper-homoscorpionate…
The complex TpBr3Cu(NCMe) catalyzes, at room temperature, the insertion of a nitrene group from PhINTs into the carbon-hydrogen…
The imido complex (dtbpe)Ni(N(2,6-(CHMe2)2C6H3)) reacts with CO and CNCH2Ph with addition at the Ni-N bond to give (dtbpe)Ni(C,N…
Analogues of fatty acids have been synthesized which contain an S-S bridge in the aliphatic chain and at the omega-carbon the…
The isolation of specific rabbit antibodies for the haptenic group 4-azido-2-nitrophenyl, is described. These antibodies bind 1.8…