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phenylnitrene

Known as: Imidogen, phenyl- 
National Institutes of Health

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2 relations

Broader (1)

Imines
nitrene

Papers overview

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2012
2012
Spin-state dependent radical stabilization in nitrenes: the unusually small singlet-triplet splitting in 2-furanylnitrene.
Geometries and energies of the triplet and singlet states of 2-furanylnitrene and 3-furanylnitrene have been calculated by using… 
2011
2011
Time-resolved resonance Raman and computational investigation of the influence of 4-acetamido and 4-N-methylacetamido substituents on the chemistry of phenylnitrene.
A time-resolved resonance Raman (TR(3)) and computational investigation of the photochemistry of 4-acetamidophenyl azide and 4-N… 
2010
2010
Magnetic trapping of atomic nitrogen and cotrapping of NH
We observe magnetic trapping of atomic nitrogen (N) and cotrapping of groundstate imidogen (NH, X3Σ−) and measure collisional… 
2009
2009
Controllable selective functionalization of a cavitand via solid state photolysis of an encapsulated phenyl azide.
Phenyl azide (1) has been encapsulated within cavitand 2 to form a 1:1 complex of 1@2 in the solid state. Subsequent irradiation… 
2007
2007
Photochemical and thermal reactions of intermediates in the phenylnitrene rearrangement inside a hemicarcerand.
Broadband irradiation (lambda > 320 nm) of hemicarceplex H(.)1 between -74 degrees C and -84 degrees C, produces encapsulated… 
2007
2007
Structure and reactivity of benzoylnitrene radical anion in the gas phase.
The open-shell benzoylnitrene radical anion, readily generated by electron ionization of benzoylazide, undergoes unique chemical… 
2005
2005
Role of conformation and electronic structure in the chemistry of ground and excited state o-pyrazolylphenylnitrenes.
The chemistry of 2-(1-pyrazolyl)- (2a) and 2-[1-(3,5-dimethylpyrazolyl]phenylnitrene (2b) has been studied in EtOH solution at… 
2004
2004
Formation of Nitroso Oxides in the Photolysis of Aromatic Azides: Analysis of Products; Reaction Kinetics and Mechanism
AbstractThe formation of nitroso oxides (ArNOO) IIa–IIc and IIf was observed in the flash photolysis of solutions of phenylazide… 
2002
2002
Substituent effects in the interconversion of phenylcarbene, bicyclo[4.1.0]hepta-2,4,6-triene, and 1,2,4,6-cycloheptatetraene.
The effect of aryl substituents on the interconversion of phenylcarbene (PC), bicyclo[4.1.0]hepta-2,4,6-triene (BCT), and 1,2,4,6… 
1997
1997
Photochemistry of pyridyl azides and diazo ketones in matrix and in solution
Abstract 
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