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mandelylthiamin

National Institutes of Health

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2017
2017
Lessons Learned from the Reactivity of Mandelylthiamin and Derivatives
Mandelylthiamin (MTh) is an accurate model of the pre-decarboxylation intermediate formed on benzoylformate decarboxylase (BFDC… 
2015
2015
Lithium-stabilized nucleophilic addition of thiamin to a ketone provides an efficient route to mandelylthiamin, a critical pre-decarboxylation intermediate.
2010
2010
Isotope effect, mechanism, and origin of catalysis in the decarboxylation of mandelylthiamin.
The mechanism of decarboxylations in water and the catalysis of mandelylthiamin (MTh) decarboxylation by pyridinium ions is… 
2009
2009
Internal return of carbon dioxide in decarboxylation: catalysis of separation and 12C/13C kinetic isotope effects.
It has been proposed that the decarboxylation of mandelylthiamin, the adduct of benzoylformate and thiamin, is uniquely catalyzed… 
2006
2006
Accelerating unimolecular decarboxylation by preassociated acid catalysis in thiamin-derived intermediates: implicating Brønsted acids as carbanion traps in enzymes.
Mandelylthiamin (MT) is formally the conjugate of thiamin and benzoylformate. It is the simplified analogue of the first covalent… 
2005
2005
Making thiamin work faster: acid-promoted separation of carbon dioxide.
The conjugate of thiamin and benzoylformate, mandelylthiamin (MTh), undergoes decarboxylation about 106 times slower than the… 
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