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acetylenedicarboxylic acid dimethyl ester

Known as: 2-butynedioic acid, dimethyl ester, dimethyl acetylenedicarboxylate 
National Institutes of Health

Related topics

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2 relations

Broader (1)

Alkynes
diethyl acetylenedicarboxylate

Papers overview

Semantic Scholar uses AI to extract papers important to this topic.
2013
2013
Dual behavior of isatin-based cyclic ketimines with dicarbomethoxy carbene: expedient synthesis of highly functionalized spirooxindolyl oxazolidines and pyrrolines.
A highly stereo-, regio-, and chemoselective method has been devised for the synthesis of a wide range of spirooxindolyl… 
Highly Cited
2011
Highly Cited
2011
Synthesis of 3,4-dihydropyridin-2(1H)-ones and 3,4-dihydro-2H-pyrans via Four-component reactions of aromatic aldehydes, cyclic 1,3-carbonyls, arylamines, and dimethyl acetylenedicarboxylate.
A protocol has been developed for the efficient synthesis of structurally diverse 3,4-dihydropyridin-2(1H)-ones and 3,4-dihydro… 
Highly Cited
2009
Highly Cited
2009
Modular functionalization of carbon nanotubes and fullerenes.
A series of highly efficient, modular zwitterion-mediated transformations have been developed which enable diverse… 
Highly Cited
2006
Highly Cited
2006
Synthesis of new 2-vinylation products of indole via a Michael-type addition reaction with dimethyl acetylenedicarboxylate and their Diels-Alder reactivity as precursors of new carbazoles.
Reaction of 4,7-dihydroindole and dimethyl acetylenedicarboxylate provided a convenient route to functionalized 2-vinylindoles… 
2006
2006
On the [2+2] cycloaddition of 2-aminothiazoles and dimethyl acetylenedicarboxylate. Experimental and computational evidence of a thermal disrotatory ring opening of fused cyclobutenes.
The reaction of 2-(phenylamino)- and 2-(dimethylamino)thiazoles with dimethyl acetylenedicarboxylate led unexpectedly to dimethyl… 
Highly Cited
2004
Highly Cited
2004
Short total synthesis of (+/-)-sceptrin.
Gifted with novel chemical features and extraordinary biological activity, sceptrin has remained a prominent unanswered synthetic… 
Highly Cited
2004
Highly Cited
2004
Multicomponent reactions of diazoamides: diastereoselective synthesis of mono- and bis-spirofurooxindoles.
This paper describes the intermolecular generation of carbonyl ylides by dirhodium(II) tetraacetate-catalyzed reaction of 3… 
Highly Cited
2000
Highly Cited
2000
Selective palladium-catalyzed cocyclotrimerization of arynes with dimethyl acetylenedicarboxylate: A versatile method for the synthesis of polycyclic aromatic hydrocarbons
Benzyne (1a) and the substituted derivatives 4,5-difluorobenzyne (1b) and 3-methoxybenzyne (2) undergo chemoselective palladium… 
Highly Cited
1997
Highly Cited
1997
Stereocontrol in Intermolecular Dirhodium(II)-Catalyzed Carbonyl Ylide Formation and Reactions. Dioxolanes and Dihydrofurans.
Ethyl diazoacetate undergoes dirhodium(II)-catalyzed reactions with aryl aldehydes to form 1,3-dioxolanes as mixtures of… 
Review
1963
Review
1963
REACTIONS OF ACETYLENECARBOXYLIC ACIDS AND THEIR ESTERS WITH NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS.
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