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C2-symmetric binaphthyl phosphortriamide

Known as: chiral HMPA 
 
National Institutes of Health

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1996-2017
02419962017

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Naphthalenes

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1937-2018
19401960198020002020
C2-symmetric binaphthyl phosphortriamide
Naphthalenes

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2013
2013
Asymmetric construction of spirocyclopentenebenzofuranone core structures via highly selective phosphine-catalyzed [3 + 2] cycloaddition reactions.
An efficient organocatalytic asymmetric [3 + 2] cycloaddition reaction between 3-substituted methylenebenzofuranone derivatives… (More)
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2012
2012
Vibrational circular dichroism spectroscopy of two chiral binaphthyl diphosphine ligands and their palladium complexes in solution.
BINAP (2,2'-diphenylphosphino-1,1'-binaphthyl) is a unique binaphthyl diphosphine ligand with axial chirality. The palladium… (More)
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2011
2011
Self-discriminating and hierarchical assembly of racemic binaphthyl-bisbipyridines and silver ions: from metallocycles to gel nanofibers.
A heterochiral metallocycle was formed by self-discriminating assembly of racemic bisbipyridines and silver ions, and further… (More)
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2011
2011
Synthesis and conformation of substituted chiral binaphthyl-azobenzene cyclic dyads with chiroptical switching capabilities.
Optically active binaphthyl-azobenezene cyclic dyads were synthesized to develop a photochromic switching molecule. Azobenezene… (More)
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2007
2007
Synthesis of C2-symmetric bisamidines: a new type of chiral metal-free Lewis acid analogue interacting with carbonyl groups.
The chiral bisamidine 5 has been prepared in just two steps from malonodinitrile. In the monocationic form this compound adopts a… (More)
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2007
2007
Design of C2-symmetric tetrahydropentalenes as new chiral diene ligands for highly enantioselective Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids.
 
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2005
2005
Absolute configuration of C2-symmetric spiroselenurane: 3,3,3',3'-tetramethyl-1,1'-spirobi[3 H,2,1]benzoxaselenole.
The enantiomers of 3,3,3',3'-tetramethyl-1,1'-spirobi[3 H,2,1]benzoxaselenole have been separated on a chiral preparative… (More)
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2003
2003
A chiral chelating diene as a new type of chiral ligand for transition metal catalysts: its preparation and use for the rhodium-catalyzed asymmetric 1,4-addition.
As a new type of chiral ligand, a C2-symmetric norbornadiene derivative (1R,4R)-2,5-dibenzylbicyclo[2.2.1]hepta-2,5-diene (1) was… (More)
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2003
2003
Remarkably stereoselective photoinduced electron-transfer reaction between zinc myoglobin and optically active binaphthyl bisviologen
We have designed and synthesized new optically active bisviologens ([BNMV]4+) containing a binaphthyl moiety to examine the… (More)
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1997
1997
Synthesis and chiroptical properties of a novel C2-symmetric binaphthyl phosphortriamide ("chiral HMPA").
By use of an asymmetric Ullmann coupling involving chiral naphthalene oxazolines 1, the title compounds were prepared in good… (More)
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