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17-oxosparteine

National Institutes of Health

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Sparteine
analogs & derivatives

Papers overview

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1996
1996
Use of site-specified tritium labelling to confirm the formation of 17-oxosparteine as a minor urinary metabolite of sparteine in man.
1. The synthesis of [17,17-3H2]-sparteine and its oral administration has enabled the specific identification of 17-oxosparteine… 
1995
1995
Mechanism of cytochrome P450 2D6-catalyzed sparteine metabolism in humans.
Two different reaction mechanisms for the formation of the two human enamine-structured sparteine metabolites by cytochrome P450… 
1993
1993
Quinolizidine alkaloids inGenista acanthoclada and its holoparasite,Cuscuta palaestina
About 20 quinolizidine alkaloids were identified inGenista acanthoclada by capillary GLC and GLC-MS, such as sparteine, 11,12… 
1988
1988
Molecular and crystal structure ofβ-isosparteine monoperchlorate
The crystal structure; determined by X rays, and the13C-NMR spectra ofβ-isosparteine perchlorate are presented. The quinolizidine… 
Highly Cited
1983
Highly Cited
1983
Accumulation of quinolizidine alkaloids in plants and cell suspension cultures: genera lupinus, cytisus, baptisia, genista, laburnum, and sophora.
The patterns of quinolizidine alkaloids in cell cultures of 10 species of Fabaceae were analyzed by high-resolution GLC and GLC… 
Highly Cited
1982
Highly Cited
1982
Localization of the Enzymes of Quinolizidine Alkaloid Biosynthesis in Leaf Chloroplasts of Lupinus polyphyllus.
Studies with purified chloroplasts of Lupinus polyphyllus LINDL. leaflets indicate that the first two enzymes of quinolizidine… 
Highly Cited
1981
Highly Cited
1981
Quinolizidine Alkaloid Composition of Plants and of Photomixotrophic Cell Suspension Cultures of Sarothamnus scoparius and Orobanche rapum-genistae
Sarothamnus scoparius Orobanche rapum-genistae S. scoparius Orobanche rapum-genistae Sarothamnus S. scoparius S. scoparius 
1981
1981
Activation of chloroplast-localized enzymes of quinolizidine alkaloid biosynthesis by reduced thioredoxin
Previous studies from the laboratory of the authors have shown that the tetracyclic quinolizidine alkaloids are synthesized in… 
1980
1980
A chloroplast‐localized lysine decarboxylase of Lupinus polyphyllus
1979
1979
A Model Mechanism for the Enzymatic Synthesis of Lupin Alkaloids
Abstract A crude enzyme preparation obtained from cell suspension cultures of Lupinus polyphyllus catalyzes the pyruvate… 
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