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spiroketalenol ether-6,7-epoxy-diyne

Known as: Z-spiroketalenol ether-6,7-epoxy-diyne 
National Institutes of Health

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2 relations

Broader (2)

DiynesEpoxy Compounds

Papers overview

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2012
2012
Palladium(II)-catalyzed stereospecific three-component domino reactions of diyne-enones, nucleophiles, and vinyl ketones.
2012
2012
Highly stereocontrolled synthesis of trans-enediynes via carbocupration of fluoroalkylated diynes
Treatment of readily prepared (Z)-6-benzyloxy-1,1,1,2-tetrafluoro-6-methyl-2-hepten-4-yne with 1.5 equiv of LHMDS in −78 °C for 1… 
2011
2011
Chain-growth cycloaddition polymerization via a catalytic alkyne [2 + 2 + 2] cyclotrimerization reaction and its application to one-shot spontaneous block copolymerization.
A cobalt-catalyzed alkyne [2 + 2 + 2] cycloaddition reaction has been applied to polymerizations yielding linear polymers via… 
2010
2010
Rhodium-catalyzed tandem nucleophilic addition/bicyclization of diyne-enones with alcohols: a modular entry to 2,3-fused bicyclic furans.
A novel, efficient and atom-economic Rh-catalyzed stereoselective tandem nucleophilic addition/bicyclization for the synthesis of… 
2010
2010
SAR studies of gymnasterkoreayne derivatives with cancer chemopreventive activities.
2002
2002
Synthesis of phthalides and 3,4-dihydroisocoumarins using the palladium-catalyzed intramolecular benzannulation strategy.
A novel method for the synthesis of phthalides and 3,4-dihydroisocoumarins via the palladium-catalyzed intramolecular… 
2002
2002
An unusual ruthenium-catalyzed cycloisomerization of alkynes and propargyl alcohols.
CpRu(NCCH3)3+PF6- catalyzes the cycloisomerization of diyne-ols to alpha,beta,gamma,delta-unsaturated aldehydes and ketones in… 
2002
2002
Template-directed synthesis of helical phenanthroline cyclophanes.
Recently the synthesis and study of assorted carbocyclic cyclophanes and cage compounds[1] has been augmented by novel… 
2001
2001
Formation of cyclopentadienyl and ruthenacyclopentadienyl derivatives through ynenyl-diyne and ynenyl-alkyne couplings onto a triruthenium cluster core.
The compound [Ru3(mu-H)(mu3-eta2-ampy)(CO)9] (1; Hampy =2-amino-6-methylpyridine) reacts with diynes RC4R in THF at reflux… 
2000
2000
Effective synthesis of aryl ethers and coumaranones employing the palladium-catalyzed enyne-diyne
Alkyl-, alkoxy-, and aryloxy-substituted conjugated enynes 1 in the presence of Pd(PPh(3))(4) catalyst smoothly underwent the… 
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