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scandium triflate

Known as: Sc(OTf)3, scandium(III) trifluoromethanesulfonate 
National Institutes of Health

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2 relations

Broader (2)

MesylatesScandium

Papers overview

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Highly Cited
2018
Highly Cited
2018
Lewis Acid Catalyzed Stereoselective Dearomative Coupling of Indolylboron Ate Complexes with Donor-Acceptor Cyclopropanes and Alkyl Halides.
Indolylboron ate complexes readily generated from 2-lithioindoles and boronic esters underwent multicomponent dearomative… 
Highly Cited
2014
Highly Cited
2014
Catalytic C6 functionalization of 2,3-disubstituted indoles by scandium triflate.
We report herein an unprecedented direct catalytic C6 functionalization reaction of 2,3-disubstituted indoles with various N-Ts… 
Review
2009
Review
2009
"Microencapsulated" and related catalysts for organic chemistry and organic synthesis.
2.6. Microencapsulated Cu(acac)2 [MC Cu(acac)2] 606 2.7. Microencapsulated Palladium [MC Pd] 607 2.8. Microencapsulated… 
Highly Cited
2008
Highly Cited
2008
Catalytic three-component Ugi reaction.
Multicomponent reactions (MCRs) are one-pot processes that combine three or more substrates simultaneously. Such processes are of… 
Highly Cited
2008
Highly Cited
2008
Efficient catalytic oxidation of alkanes by Lewis acid/[Os(VI)(N)Cl4]- using peroxides as terminal oxidants. Evidence for a metal-based active intermediate.
The oxidation of alkanes by various peroxides ((t)BuOOH, H2O2, PhCH2C(CH3)2OOH) is efficiently catalyzed by [Os(VI)(N)Cl4… 
Highly Cited
2006
Highly Cited
2006
Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multi-substituted pyrrolidines.
A tandem ring-opening-cyclization reaction of cyclopropanes with imines in the presence of 5 mol% of scandium triflate was… 
Highly Cited
2004
Highly Cited
2004
Lewis acids catalyze the addition of allylboronates to aldehydes by electrophilic activation of the dioxaborolane in a closed transition structure.
This study addressed the mechanism of the recently reported Lewis acid-catalyzed manifold for additions of allylboronates to… 
Highly Cited
2003
Highly Cited
2003
Secondary benzylation using benzyl alcohols catalyzed by lanthanoid, scandium, and hafnium triflate.
The combination of a secondary benzyl alcohol and a metal triflate (e.g., La, Yb, Sc, and Hf triflate) in nitromethane was a… 
Highly Cited
2002
Highly Cited
2002
Novel facile synthesis of 2,2,4 substituted 1,2-dihydroquinolines via a modified Skraup reaction
Highly Cited
2002
Highly Cited
2002
Acceleration effect of Lewis acid in allylboration of aldehydes: catalytic, regiospecific, diastereospecific, and enantioselective synthesis of homoallyl alcohols.
The addition of pinacol allylboronic esters to aromatic and aliphatic aldehydes smoothly occurred at -78 degrees C in toluene in… 
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