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n-butyllithium

Known as: n-BuLi 
National Institutes of Health

Related topics

Related topics

2 relations

Broader (1)

Organometallic Compounds
tert-butyllithium

Papers overview

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2013
2013
Selectivity of Br/Li exchange and deprotonation of 4,4'-dibromo-3,3'-bithiophene for synthesis of symmetrical and unsymmetrical dithienoheteroaromatic rings.
The novel selective synthesis of symmetrical and unsymmetrical dithienoheteroaromatic rings (DTHAs) has been developed via… 
2010
2010
Si-H bond activation of alkynylsilanes by group 4 metallocene complexes.
The reactivity of variously substituted alkynylsilanes toward selected group 4 metallocene complexes was investigated. Reactions… 
2009
2009
Total synthesis of methyl sarcophytoate, a marine natural biscembranoid.
The total synthesis of methyl sarcophytoate (1), a marine natural biscembranoid, has been achieved by the thermal Diels-Alder… 
2009
2009
Lithiation-electrophilic trapping of N-sulfonyl-activated ethylene aziridines.
A detailed study on the lithiation-electrophilic trapping of N-sulfonyl ethylene aziridines is described. The optimum results… 
2003
2003
Aminoalkoxide-mediated formation and stabilization of phenylpyridyllithium: straightforward access to phenylpyridine derivatives.
It is shown that lithium aggregates promoted the efficient metalation of phenylpyridines and stabilization of… 
2002
2002
First direct C-2-Lithiation of 4-DMAP. Convenient access to reactive functional derivatives and ligands.
The first direct alpha-lithiation of 4-DMAP has been performed via reaction with the BuLi-Me(2)N(CH(2))(2)OLi (BuLi-LiDMAE… 
2002
2002
(-)-Sparteine-mediated metalation of ferrocenesulfonates. The first case of double asymmetric induction of ferrocene planar chirality.
[reaction: see text] A new process for induction of planar chirality via a matched chiral-directed metalation group (DMG… 
2002
2002
First direct lithiation of 2-pyridylpiperazine on solid phase.
[reaction: see text] The first direct lithiation of a pyridine derivative on solid phase has been realized. Metalation of polymer… 
2001
2001
Carbon-carbon bond formation of alkenylphosphonates by aldehyde insertion into zirconacycle phosphonates.
Ethyl 1-butynylphosphonate reacts with Cp(2)ZrCl(2)/2n-BuLi to give a three-membered zirconacycle that readily inserts aldehydes… 
Highly Cited
2000
Highly Cited
2000
Unusual C-6 Lithiation of 2-Chloropyridine-Mediated by BuLi-Me(2)N(CH(2))(2)OLi. New Access to 6-Functional-2-chloropyridines and Chloro-bis-heterocycles.
The reaction of 2-chloropyridine with alkylithium generally results in nucleophilic addition leading to the loss of chlorine atom… 
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