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iodosobenzene

Known as: iodosylbenzene 
National Institutes of Health

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Iodobenzenes

Papers overview

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Highly Cited
2012
Highly Cited
2012
Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin
Fluorine's Smooth Introduction Carbon-fluorine bonds are emerging as increasingly versatile constituents of drugs, agrochemicals… 
Highly Cited
2007
Highly Cited
2007
Synthesis, characterization, and reactivities of manganese(V)-oxo porphyrin complexes.
The reactions of manganese(III) porphyrin complexes with terminal oxidants, such as m-chloroperbenzoic acid, iodosylarenes, and H… 
Highly Cited
2004
Highly Cited
2004
Catalytic sulfoxidation and epoxidation with a Mn(III) triazacorrole: evidence for a "third oxidant" in high-valent porphyrinoid oxidations.
The reaction between (TBP)8(Cz)Mn(III) (1) and the oxygen atom donors iodosylbenzene (PhIO) or p-cyanodimethylaniline-N-oxide… 
Highly Cited
2002
Highly Cited
2002
Anionic ligand effect on the nature of epoxidizing intermediates in iron porphyrin complex-catalyzed epoxidation reactions.
We have studied an anionic ligand effect in iron porphyrin complex-catalyzed competitive epoxidations of cis- and trans-stilbenes… 
Highly Cited
2002
Highly Cited
2002
Iron(III) [bond] Salen complexes as enzyme models: mechanistic study of oxo(salen)iron complexes oxygenation of organic sulfides.
The oxidation of a series of para-substituted phenyl methyl sulfides was carried out with several oxo(salen)iron (salen = N,N… 
Highly Cited
2001
Highly Cited
2001
High-Valent Manganese Corroles and the First Perhalogenated Metallocorrole Catalyst.
On pyrrole! The pyrrole-based corrole ligands can offer an alternative to porphyrin systems. The manganese corroles 1-4 are… 
Highly Cited
1997
Highly Cited
1997
Cooperativity in oxidations catalyzed by cytochrome P450 3A4.
Cytochrome P450 (P450) 3A4 is the most abundant human P450 and oxidizes a diversity of substrates, including various drugs… 
Highly Cited
1996
Highly Cited
1996
Dendrimer-metalloporphyrins: Synthesis and catalysis
A new class of sterically hindered dendrimer-metalloporphyrins was synthesized for use as shape-selective oxidation catalysts. A… 
Highly Cited
1996
Highly Cited
1996
Evidence for a 1-Electron Oxidation Mechanism in N-Dealkylation of N,N-Dialkylanilines by Cytochrome P450 2B1
Many enzymes catalyze N-dealkylations of alkylamines, including cytochrome P450 (P450) and peroxidase enzymes. Peroxidases… 
Highly Cited
1976
Highly Cited
1976
Cytochrome P450 as an oxene transferase.
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