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Highly efficient catalase activity of metallocorroles.
The iron(iii) complex of a bipolar and amphiphilic corrole, which binds strongly to proteins and undergoes protein-mediated cellular uptake, catalyzes the decomposition of hydrogen peroxide fasterExpand
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The First Direct Synthesis of Corroles from Pyrrole.
The solvent-free, catalyst-free condensation of pyrrole and aldehydes provides an extremely facile synthetic pathway to novel corroles [Eq. (1); Ar=C6 F5 , 2,6-F2 C6 H3 , 2,6-Cl2 C6 H3 ]. The productExpand
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Albumin-conjugated corrole metal complexes: extremely simple yet very efficient biomimetic oxidation systems.
  • A. Mahammed, Z. Gross
  • Chemistry, Medicine
  • Journal of the American Chemical Society
  • 11 February 2005
An extremely simple biomimetic oxidation system, consisting of mixing metal complexes of amphiphilic corroles with serum albumins, utilizes hydrogen peroxide for asymmetric sulfoxidation in up to 74%Expand
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Oxygen atom transfer reactions from isolated (oxo)manganese(V) corroles to sulfides.
A series of five free-base corroles were metalated and brominated to form 10 manganese(III) corroles. Two of the free-base corroles and six manganese(III) corroles were analyzed by X-rayExpand
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Iron and manganese corroles are potent catalysts for the decomposition of peroxynitrite.
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Superoxide dismutase activity of corrole metal complexes.
The first report regarding SOD activity of metallocorroles, investigated via the combination of the cytochrome C assay, pulse radiolysis, and electrochemistry, is used for identifying the mainExpand
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Highly selective chlorosulfonation of tris(pentafluorophenyl)corrole as a synthetic tool for the preparation of amphiphilic corroles and metal complexes of planar chirality.
[reaction: see text]. The chlorosulfonation of tris(pentafluorophenyl)corrole proceeds with an extremely high selectivity as to afford one out of 139 possible isomers in very high yield. TheExpand
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Remarkable Effects of Metal, Solvent, and Oxidant on Metalloporphyrin-Catalyzed Enantioselective Epoxidation of Olefins
Three metal complexes of one particular homochiral porphyrin were investigated as catalysts for enantioselective epoxidation of unfunctionalized olefins under various reaction conditions. Much betterExpand
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How acidic are corroles and why
The pH-dependent absorption and emission spectra of the water-soluble 2,17-disulphonato-5,10,15-tris(pentafluorophenyl)corrole revealed that its inner-core nitrogen atoms can be both protonated andExpand
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Exploring the photoexcited triplet states of aluminum and tin corroles by time-resolved Q-band EPR
The photoexcited triplet states of three 5,10, 15-tris(pentafluorophenyl)corroles (tpfc), hosting Sn(IV) and Al(III) in their core, namely, Sn(Cl)(tpfc), Al(pyr)2(tpfc) and Al(pyr)2(tpfc-Br8), wereExpand
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