guanacastepene A
National Institutes of Health
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The origins of different stereoselectivities observed experimentally in the alkylations of azulenone precursors in the…
An efficient intramolecular Diels-Alder (IMDA) strategy for the construction of the [5-7-6] tricyclic core (18) of…
[reaction: see text] The stereoselectivity of the key epoxidation step in the synthesis of guanacastepene A is shown to be…
[reaction: see text] The goal of the total synthesis of guanacastepene A served as a focus to bring together several chemical…
The hydroazulene core of guanacastepene A has been synthesized in five steps from commercially available starting materials using…
[reaction: see text] An approach to the highly functionalized tricyclic core of guanacastepene A has been developed using a…
[reaction: see text] A synthesis of the tricyclic [5-7-6] skeleton of guanacastepene A is described. The six-membered ring of…
[reaction: see text] As a part of studies aimed toward the total synthesis of biologically important natural product…
Commercially available tribromoethylene has been converted to ketoepoxide 15, an advanced intermediate in the total synthesis of…