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epimerization

National Institutes of Health

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Stereochemistry (Molecular Function)

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2006
2006
First enantioselective synthesis of ( )-talaumidin, a neurotrophic diaryltetrahydrofuran-type lignan
2003
2003
Epimerization of 2'-carbonylalkyl-C-glycosides via enolation, beta-elimination and intramolecular cycloaddition.
Treatment of 2'-carbonyl-alpha-C-glycopyranosides of gluco, galacto, manno, 2-deoxy, and 2-azido sugars with 4% NaOMe resulted in… 
Highly Cited
2002
Highly Cited
2002
Technical note: epimerization of ergopeptine alkaloids in organic and aqueous solvents.
Purified ergopeptine alkaloids are often used in studies related to tall fescue toxicosis without regard to epimerization that… 
Highly Cited
2000
Highly Cited
2000
Synthesis of highly epimerizable N-protected α-amino aldehydes of high enantiomeric excess
1999
1999
Discovery Through Total Synthesis-Epimerization at C7 in the CP Compounds: Is (7S)-CP-263,114 a Fermentation Product?
Sometimes a surprise can occur in a total synthesis. The preparative investigation of the title compound CP-263,114 and of CP-225… 
1994
1994
Epimerization of the D-valine portion in the biosynthesis of actinomycin D.
In the biosynthesis of actinomycin, the multifunctional actinomycin synthetase II (ACMS II) assembles 4-methyl-3… 
1984
1984
Epimerization of benzylpenicilloic acid in alkaline media.
5R,6R-Benzylpenicilloic acid was found to epimerize slowly in alkaline media to 5S,6R-benzylpenicilloic acid until equilibrium… 
Highly Cited
1981
Highly Cited
1981
2,3-Dehydro-4-epi-N-acetylneuraminic acid; a neuraminidase inhibitor.
1978
1978
Synthesis of both optical isomers of insect juvenile hormone III and their affinity for the juvenile hormone-specific binding protein of Manduca sexta.
Highly Cited
1971
Highly Cited
1971
The mechanism of action of the enzyme uridine diphosphoglucose 4-epimerase. Proof of an oxidation-reduction mechanism with direct transfer of hydrogen between substrate and the B-position of the…
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