dioxirane
National Institutes of Health
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This paper describes a highly chemo- and enantioselective epoxidation of conjugated cis-enynes using readily available glucose…
Representative Boc-protected and acetyl-protected peptide methyl esters bearing alkyl side chains undergo effective oxidation…
The reaction modes of the three isomers, carbonyl oxide (A), dioxirane (B), and methylenebis(oxy) (C), with ethylene (E) were…
An 8-(13)C-labeled guanosine derivative, 2',3',5'-O-tert-butyldimethylsilyl-N-tert-butyldimethylsilyl-8-(13)C-guanosine, was…
[see reaction]. This paper describes an enantioselective epoxidation of terminal olefins using chiral ketone 3 as catalyst and…
The electronic character of peroxyformic acid and dioxirane has been clarified by the analysis of donor-acceptor interactions in…
Geraniol and its 1-methyl derivative (regiochemical probes) and a set of methyl- and tert-butyl-substituted chiral allylic…
The performance of the B3LYP density functional theory calculations has been studied for the epoxidation reactions of ethylene…