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Enediynes

Known as: Enediyne Group, Enediynes [Chemical/Ingredient] 
Compounds with triple bonds to each side of a double bond. Many of these are CYTOTOXINS and are researched for use as CYTOTOXIC ANTIBIOTICS.
National Institutes of Health

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20'-deschloro-C-1027C 1027N1999-A2Shishijimicin A
In Bloodagonistsantagonists & inhibitorsaspects of radiation effects

Papers overview

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2010
2010
Memory of chirality in cascade rearrangements of enediynes.
The cascade rearrangement of chiral enediynes 1c-e, involving successively 1,3-proton shift, Saito-Myers cyclization, 1,5… 
Highly Cited
2005
Highly Cited
2005
Computational studies on the cyclizations of enediynes, enyne-allenes, and related polyunsaturated systems.
Quantum chemical studies of cyclizations of enediynes and enyne-allenes have proven to be computationally tractable thanks to the… 
2005
2005
A transition-metal-catalyzed enediyne cycloaromatization.
The pentamethylcyclopentadienyl iron cation, generated from [(eta5-C5Me5)Fe(NCMe)3]PF6, triggers the room temperature… 
Highly Cited
2004
Highly Cited
2004
5-Exo-dig radical cyclization of enediynes: the first synthesis of tin-substituted benzofulvenes.
[reaction: see text] Bu(3)Sn-mediated 5-exo-dig radical cyclization of diaryl enediynes provides a mild and efficient approach to… 
Highly Cited
2003
Highly Cited
2003
Ambient temperature activation of haloporphyrinic-enediynes: electronic contributions to bergman cycloaromatization.
We have synthesized the nickel(II) 2,3-bis(haloethynyl)-5,10,15,20-tetraphenylporphyrins with -Br (2a) or -I (2b) at the alkyne… 
Highly Cited
2002
Highly Cited
2002
C1-c5 photochemical cyclization of enediynes.
This study reports a new photochemical cyclization of tetrafluoropyridinyl (TFP)-substituted enediynes that is accompanied with… 
Highly Cited
2001
Highly Cited
2001
Carbonyl- and carboxyl-substituted enediynes: synthesis, computations, and thermal reactivity.
The influence of electron-withdrawing groups (carbonyl and carboxyl) at the alkyne termini on the reactivity of enediynes was… 
2001
2001
UDFT and MCSCF descriptions of the photochemical Bergman cyclization of enediynes.
Several singlet and triplet potential energy surfaces (PES) for the Bergman cyclization of cis-1,5-hexadiyne-3-ene (1a) have been… 
Highly Cited
1998
Highly Cited
1998
Photochemical Rearrangement of Enediynes: Is a "Photo-Bergman" Cyclization a Possibility?
The enediynes 1 and 2 were photolyzed in 2-propanol to yield products akin to those analogous to a thermal Bergman cyclization… 
1985
1985
Cobalt-mediated steroid synthesis
Abstract 
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