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Cyclopropanes

Known as: Cyclopropanes [Chemical/Ingredient] 
Three-carbon cycloparaffin cyclopropane (the structural formula (CH2)3) and its derivatives.
National Institutes of Health

Related topics

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Narrower (44)

1-amino-2-methylenecyclopropane-1-carboxylic acid1-benzylcyclopropylamine1-hydroxycyclopropanecarboxylic acid phosphate1-methylcyclopropene
In BloodMetaraminolPropaneagonists

Papers overview

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Highly Cited
2016
Highly Cited
2016
Ring Expansion of Donor-Acceptor Cyclopropane via Substituent Controlled Selective N-Transfer of Oxaziridine: Synthetic and Mechanistic Insights.
A distinctive N-substituent controlled electrophilic N-transfer of oxaziridines with donor-acceptor cyclopropanes in the presence… 
Highly Cited
2015
Highly Cited
2015
Lewis Acid/Rhodium-Catalyzed Formal [3 + 3]-Cycloaddition of Enoldiazoacetates with Donor-Acceptor Cyclopropanes.
A formal [3 + 3]-cycloaddition of enoldiazoacetates with donor-acceptor cyclopropanes was realized by the combination of a Lewis… 
Highly Cited
2013
Highly Cited
2013
Ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes via a N-sulfonyl-1,2,3-triazole intermediate.
Regioselective ring expansion of alkynyl cyclopropanes to highly substituted cyclobutenes was developed. The reaction involves a… 
Highly Cited
2011
Highly Cited
2011
Nucleophilic ring opening of cyclopropane hemimalonates using internal Brønsted acid activation.
The reaction of cyclopropanes, geminally disubstituted with one carboalkoxy and one carbohydroxy group, undergoes ring-opening… 
2010
2010
One-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcohols.
Highly enantio- and diastereoselective methods for the synthesis of a variety of cyclopropyl alcohols are reported. These methods… 
Highly Cited
2009
Highly Cited
2009
anti-Oligoannelated THF moieties: synthesis via push-pull-substituted cyclopropanes.
The first synthesis of anti-fused oligoannelated THF moieties is reported. The key transformation of the synthetic sequence… 
2009
2009
Lewis acid or Brønsted acid catalyzed reactions of vinylidene cyclopropanes with activated carbon-nitrogen, nitrogen-nitrogen, and iodine-nitrogen double-bond-containing compounds.
Lewis acid or Brønsted acid catalyzed reactions of vinylidene cyclopropanes (VDCPs), 1, with activated carbon-nitrogen, nitrogen… 
Highly Cited
2006
Highly Cited
2006
Converting gem-dimethyl groups into cyclopropanes via Pd-catalyzed sequential C-H activation and radical cyclization.
A novel route to the synthesis of cyclopropane derivatives is described. 1,1-Dimethyls in 2-(1,1-dimethylalkyl)dimethyloxazolines… 
Highly Cited
1993
Highly Cited
1993
A CCSD (T) investigation of carbonyl oxide and dioxirane. Equilibrium geometries, dipole moments, infrared spectra, heats of formation and isomerization energies
Highly Cited
1989
Highly Cited
1989
Stereoselective cyclopropanations with vinylcarbenoids
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