BINAP
National Institutes of Health
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The Michael reaction is one of the most general and versatile methods for carbon-carbon bond formation,1 and its Mukaiyama…
A kinetic study on the Rh/binap-catalyzed 1,4-addition of phenylboronic acid using reaction calorimetry revealed that the…
[reaction: see text] Catalytic asymmetric allylation of 3,4-dihydro-6,7-dimethoxyisoquinoline was carried out using…
[structure: see text] A recently developed BINAP derivative with trimethylsilyl substituents on the 4- and 4'-positions of the…
A family of tunable precatalysts Ru(4,4'-BINAP)(chiral diamine)Cl2 was synthesized and used for highly enantioselective…
[reaction: see text] The chiral palladium complex generated in situ from [Pd(eta(3)-allyl)Cl](2) and (R)-BINAP is a good catalyst…
The mechanism of asymmetric hydrogenation of α-(acylamino)acrylic esters with Ru(CH3COO)2[(S)-binap] (BINAP = 2,2‘-bis…
Stereomutation of a BIPHEP/RuCl2 /diamine complex (shown schematically) is possible because of the conformational flexibilty of…