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- Publications
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Chiral Brønsted acid-catalyzed direct Mannich reactions via electrophilic activation.
- D. Uraguchi, M. Terada
- Chemistry, Medicine
- Journal of the American Chemical Society
- 9 April 2004
It was found that the phosphoric acid derivatives of general structure 1 serve as highly effective catalysts for the direct addition of acetyl acetone to N-Boc-protected arylimines. The beneficial… Expand
Dendritic Cell Maturation Overrules H-2d–Mediated Natural Killer T (Nkt) Cell Inhibition
- Y. Ikarashi, R. Mikami, +8 authors L. Zitvogel
- Biology, Medicine
- The Journal of experimental medicine
- 15 October 2001
Given the broad expression of H-2 class Ib molecules on hematopoietic cells, antigen presentation pathways among CD1d expressing cells might tightly regulate CD1d-restricted natural killer T (NKT)… Expand
Axially chiral guanidine as enantioselective base catalyst for 1,4-addition reaction of 1,3-dicarbonyl compounds with conjugated nitroalkenes.
- M. Terada, H. Ube, Y. Yaguchi
- Chemistry, Medicine
- Journal of the American Chemical Society
- 11 January 2006
A new strategy for designing chiral guanidine molecules is presented, which features the introduction of an axially chiral binaphthyl backbone. The axially chiral guanidine catalysts thus developed… Expand
Binaphthol-derived phosphoric acid as a versatile catalyst for enantioselective carbon-carbon bond forming reactions.
- M. Terada
- Chemistry, Medicine
- Chemical communications
- 18 August 2008
Binaphthol-derived monophosphoric acids have been designed as novel chiral Brønsted-acid catalysts. The chiral phosphoric acids thus developed function as efficient enantioselective catalysts for a… Expand
Organocatalytic asymmetric aza-Friedel-Crafts alkylation of furan.
- D. Uraguchi, K. Sorimachi, M. Terada
- Chemistry, Medicine
- Journal of the American Chemical Society
- 1 September 2004
A new asymmetric entry of the 1,2-aza-Friedel-Crafts reaction catalyzed by a chiral phosphoric acid is described. The present reaction has provided an atom-economical route to furan-2-ylamine… Expand
Enantioselective friedel-crafts reaction of electron-rich alkenes catalyzed by chiral Brønsted acid.
- M. Terada, K. Sorimachi
- Chemistry, Medicine
- Journal of the American Chemical Society
- 17 January 2007
We present the first enantioselective catalysis of the Friedel−Crafts reaction via activation of electron-rich multiple bonds by a chiral Bronsted acid. The reaction of various indole derivatives… Expand
High substrate/catalyst organocatalysis by a chiral Brønsted acid for an enantioselective aza-ene-type reaction.
- M. Terada, Kyoko Machioka, K. Sorimachi
- Chemistry, Medicine
- Angewandte Chemie
- 27 March 2006
Chiral Phosphoric Acids as Versatile Catalysts for Enantioselective Carbon-Carbon Bond Forming Reactions
- M. Terada
- Chemistry
- 29 January 2010
An inventive approach to the development of chiral Bronsted acid catalysis, to enable catalysts which possess strong acid functionalities, has been accomplished. Among the various organic Bronsted… Expand
Axially chiral guanidine as highly active and enantioselective catalyst for electrophilic amination of unsymmetrically substituted 1,3-dicarbonyl compounds.
- M. Terada, M. Nakano, H. Ube
- Chemistry, Medicine
- Journal of the American Chemical Society
- 24 November 2006
A newly designed axially chiral guanidine is found to function as an effective platform for asymmetric induction at the alpha-carbon of unsymmetrically substituted 1,3-dicarbonyl compounds. Highly… Expand