BINAP, 2-naphthol
National Institutes of Health
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The copper-catalyzed conjugate addition (CA) of organometallic reagents to α,β-unsaturated carbonyl compounds is one of the most…
A rhodium-(S)-xyl-BINAP complex-catalyzed tandem formate decarbonylation and [2 + 2 + 1] carbonylative cyclization is described…
The development of a Ni(II) (S)-Tol-BINAP-catalyzed enantioselective alkylation of N-acylthiazolidinethiones with trimethyl…
The mechanism of asymmetric hydrogenation of α-(acylamino)acrylic esters with Ru(CH3COO)2[(S)-binap] (BINAP = 2,2‘-bis…
A catalytic enantioselective aza-Diels-Alder reaction of imines has been developed. The reaction of N-tosyl alpha-imino ester…
In situ IR spectroscopy and transmetalation experiments confirm a postulated catalytic cycle. The metalloenolate 1 describes the…
The past few years have witnessed a profusion of highly efficient, catalytic, enantioand diastereoselective alkylations of…
Whereas the direct reduction of aryl triflates affords mainly phenols and some arenes, the presence of a catalytic amount of…