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4-thiofuranoid glycal

National Institutes of Health

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SiloxanesThiophenes

Papers overview

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2018
2018
Stereodivergent approach in the protected glycal synthesis of L-vancosamine, L-saccharosamine, L-daunosamine and L-ristosamine involving a ring-closing metathesis step
In this paper, a new access to several chiral 3-aminoglycals as potential precursors for glycosylated natural products is… 
2011
2011
Accessing C-1 phosphonylated 2-acylamino uronic acids via 2-nitro-glycals.
Two approaches are described for the synthesis of 2-acylamino uronic acid glycosyl phosphonates from readily accessible D-glucal… 
2010
2010
Studies on the Zn(II)-mediated electrophilic selenocyclization and elimination of 3,4-O-isopropylidene-protected hydroxyalkenyl sulfides: synthesis of a 2-phenylselenenyl glycal.
2009
2009
Reactions of phenyl and ethyl 2-O-sulfonyl-1-thio-alpha-D-manno- and beta-D-glucopyranosides with thionucleophiles.
2008
2008
Palladium(II)-catalyzed rearrangement of glycal trichloroacetimidates: application to the stereoselective synthesis of glycosyl ureas.
The research on the area of glycosyl urea derivatives, in which the O- and N-glycosidic bonds are replaced with the urea… 
2007
2007
Palladium-catalyzed glycal imidate rearrangement: formation of alpha- and beta-N-glycosyl trichloroacetamides.
A novel palladium(II)-catalyzed stereoselective synthesis of alpha- and beta-N-glycosyl trichloroacetamides has been developed… 
2007
2007
Synthesis of beta-C-galacto-pyranosides with fluorine on the pseudoanomeric substituent.
[reaction: see text] beta-C-galacto-Pyranosides with CHF and CF2 substitutes for the glycosidic oxygen were prepared through a… 
2004
2004
Novel stereoselective entry to 2'-beta-carbon-substituted 2'-deoxy-4'-thionucleosides from 4-thiofuranoid glycals.
2'-Beta-methyl- and 2'-beta-hydroxymethyl-2'-deoxy-4'-thionucleosides have been synthesized through PhSeCl-mediated electrophilic… 
2003
2003
Stereoselective synthesis of 2'-beta-carbon-substituted 2'-deoxy-4'-thioribonucleosides from 4-thiofuranoid glycal.
The 4-thiofuranoid glycal 6 was converted into 1-chlorinated derivative 7 through LDA lithiation. When 7 was treated with LTMP… 
1990
1990
Synthesis and reactions of leucrose and its exocyclic glycal.
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