Stereodivergent approach in the protected glycal synthesis of L-vancosamine, L-saccharosamine, L-daunosamine and L-ristosamine involving a ring-closing metathesis step

@article{Nocquet2018StereodivergentAI,
  title={Stereodivergent approach in the protected glycal synthesis of L-vancosamine, L-saccharosamine, L-daunosamine and L-ristosamine involving a ring-closing metathesis step},
  author={Pierre-Antoine Nocquet and A. Mac{\'e} and Fr{\'e}d{\'e}ric Legros and J. Lebreton and G. Dujardin and Sylvain Collet and A. Martel and B. Carboni and F. Carreaux},
  journal={Beilstein Journal of Organic Chemistry},
  year={2018},
  volume={14},
  pages={2949 - 2955}
}
  • Pierre-Antoine Nocquet, A. Macé, +6 authors F. Carreaux
  • Published 2018
  • Chemistry, Medicine
  • Beilstein Journal of Organic Chemistry
  • In this paper, a new access to several chiral 3-aminoglycals as potential precursors for glycosylated natural products is reported from a common starting material, (−)-methyl-L-lactate. The stereodivergent strategy is based on the implementation of a ring-closing metathesis of vinyl ethers as key step of reaction sequences developed. 
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