zirconocene
National Institutes of Health
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Characterizing reactive organometallic intermediates is critical for understanding the mechanistic aspects of metal-mediated…
A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various…
The mechanism of reversible alkyne coupling at zirconium was investigated by examination of the kinetics of…
The complete catalytic cycle for the intramolecular hydroamination/cyclisation (IHC) of 4,5-hexadien-1-ylamine (1) by a…
A family of isolable, well-defined bis-indenyl zirconium sandwich complexes, (eta(5)-C(9)H(5)-1,3-R(2))(eta(9)-C(9)H(5)-1,3-R(2…
Structural limitations in small cyclic hydrocarbons are a longstanding challenge to chemistry, leading to molecules with unusual…
The copolymerization of propene with ethene in feed concentrations up to 9 mol-% ethene was investigated in dependence on…
[reaction: see text]. Hydrozirconation of internal and terminal alkynes followed by in situ transmetalation to dimethylzinc and…