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zirconocene

National Institutes of Health

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Zirconocene dichloride

Papers overview

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Highly Cited
2011
Highly Cited
2011
Zirconocene and Si-tethered diynes: a happy match directed toward organometallic chemistry and organic synthesis.
Characterizing reactive organometallic intermediates is critical for understanding the mechanistic aspects of metal-mediated… 
2008
2008
Mechanism of reversible alkyne coupling at zirconocene: ancillary ligand effects.
The mechanism of reversible alkyne coupling at zirconium was investigated by examination of the kinetics of… 
2007
2007
Intramolecular hydroamination/cyclisation of aminoallenes mediated by a neutral zirconocene catalyst: a computational mechanistic study.
The complete catalytic cycle for the intramolecular hydroamination/cyclisation (IHC) of 4,5-hexadien-1-ylamine (1) by a… 
2004
2004
Zirconium sandwich complexes with eta(9) indenyl ligands: well-defined precursors for zirconocene-mediated coupling reactions.
A family of isolable, well-defined bis-indenyl zirconium sandwich complexes, (eta(5)-C(9)H(5)-1,3-R(2))(eta(9)-C(9)H(5)-1,3-R(2… 
Highly Cited
2003
Highly Cited
2003
Zirconocene-catalyzed propene polymerization: a quenched-flow kinetic study.
The kinetics of propene polymerization catalyzed by ansa-metallocenes were studied using quenched-flow techniques. Two catalyst… 
Highly Cited
2003
Highly Cited
2003
One-pot synthetic routes to multiply substituted indene derivatives by hydrolysis of zirconocene-mediated intermolecular coupling reactions of aromatic ketones and alkynes.
Two one-pot multicomponent synthetic methods for highly substituted indenes are described. The intermolecular coupling of… 
Highly Cited
2002
Highly Cited
2002
Activation of dimethyl zirconocene by methylaluminoxane (MAO)-size estimate for Me-MAO(-) anions by pulsed field-gradient NMR.
In a study of the reaction system MAO/(C5H5)2ZrMe2, the size of the ion pair [(C5H5)2Zr(mu-Me)2AlMe2]+ [Me-MAO]- was determined… 
2002
2002
Zirconocene‐catalyzed propene‐ethene copolymer elastomers: Kinetic investigations at low ethene concentration and characterization of microstructure
The copolymerization of propene with ethene in feed concentrations up to 9 mol-% ethene was investigated in dependence on… 
2001
2001
Tandem zirconocene homologation-aldimine allylation.
[reaction: see text]. Hydrozirconation of internal and terminal alkynes followed by in situ transmetalation to dimethylzinc and… 
1994
1994
Novel Lewis acid catalysis in organic synthesis
Abstract 
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