vinylsilane
National Institutes of Health
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Bissilyl enal, prepared by a Mannich reaction of 3,3-bissilyl aldehyde with formaldehyde, has proven to be a useful linchpin in…
The reaction of a variety of alkynes with N(2)CHSiMe(3), in the presence of Cp*RuCl(cod) as the catalyst precursor, leads to the…
Chiral dicationic palladium complex-catalyzed vinylation and dienylation of glyoxylate with vinylsilanes and dienylsilanes to…
We report here our full results concerning the possibility of generating in situ from a stable and readily available ruthenium(II…
A series of novel multisubstituted vinylsilanes are prepared regio- and stereoselectively by carbozirconation of various…
Highly efficient O-silylation of alcohol with vinylsilane was developed using a catalyst system consisting of [(COE)(2)RhCl](2…
The development of the Lewis acid-catalyzed alkenylation using trimethylvinylsilanes is described. Both aliphatic and aromatic…
Free-radical mediated cyclizative carbonylations of azaenynes were carried out using TTMSS as a radical mediator to compare the…
A vinylsilane-containing alpha-amino acid and alpha,alpha-disubstituted alpha-amino acid 2 having two contiguous asymmetric…
The palladium-catalyzed desilylation-arylation of substituted vinylsilanes by p-iodoanisole in the presence of bidentate…