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vinylsilane

National Institutes of Health

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2 relations

Broader (2)

SilanesVinyl Compounds

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Highly Cited
2012
Highly Cited
2012
Prins cyclization of bis(silyl) homoallylic alcohols to form 2,6-cis-tetrahydropyrans containing a geometrically defined exocyclic vinylsilane: efficient synthesis of ring B of the bryostatins.
Bryostatins are a class of complex macrolides produced by a bacterial symbiont of the marine bryozoan Bugula neritina (Figure 1… 
Highly Cited
2011
Highly Cited
2011
Formation of vinyl-, vinylhalide- or acyl-substituted quaternary carbon stereogenic centers through NHC-Cu-catalyzed enantioselective conjugate additions of Si-containing vinylaluminums to…
A catalytic method for enantioselective conjugate addition (ECA) of Si-containing vinylaluminum reagents to β-substituted… 
2010
2010
Ruthenium-catalyzed synthesis of functional conjugated dienes via addition of two carbene units to alkynes.
The reaction of a variety of alkynes with N(2)CHSiMe(3), in the presence of Cp*RuCl(cod) as the catalyst precursor, leads to the… 
2009
2009
Highly enantioselective alkenylation of glyoxylate with vinylsilane catalyzed by chiral dicationic palladium(II) complexes.
Chiral dicationic palladium complex-catalyzed vinylation and dienylation of glyoxylate with vinylsilanes and dienylsilanes to… 
Highly Cited
2008
Highly Cited
2008
Why does fluoride anion accelerate transmetalation between vinylsilane and palladium(II)-vinyl complex? Theoretical study.
Transmetalation between palladium(II)-vinyl complex and vinylsilane was theoretically investigated with the DFT and MP2 to MP4… 
2006
2006
Enantioselective Scandium-Catalyzed Vinylsilane Additions: A New Approach to the Synthesis of Enantiopure β,γ-Unsaturated α-Hydroxy Acid Derivatives
The development of the Lewis acid-catalyzed alkenylation using trimethylvinylsilanes is described. Both aliphatic and aromatic… 
Highly Cited
2005
Highly Cited
2005
Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.
The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access… 
Highly Cited
2003
Highly Cited
2003
Ruthenium-catalyzed vinylsilane synthesis and cross-coupling as a selective approach to alkenes: benzyldimethylsilyl as a robust vinylmetal functionality.
[reaction: see text] Ruthenium-catalyzed alkyne hydrosilylation or silyl-alkyne Alder ene reactions provide entry into… 
2001
2001
Chirality transferring [3,3] sigmatropic rearrangement of (1-Acyloxy-2-alkenyl)trianlkylsilane synthesis of optically active vinylsilane-containing alpha-amino acid.
A vinylsilane-containing alpha-amino acid and alpha,alpha-disubstituted alpha-amino acid 2 having two contiguous asymmetric… 
Highly Cited
1997
Highly Cited
1997
Stereoselective Synthesis of Dihydropyrans via Vinylsilane-Terminated Cyclizations of Ester-Substituted Oxycarbenium Ion Intermediates
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