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tris(pyrazolyl)borate

National Institutes of Health

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BoratesPyrazoles

Papers overview

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2015
2015
Manifestation of π-π stacking interactions in luminescence properties and energy transfer in aromatically-derived Tb, Eu and Gd tris(pyrazolyl)borate complexes.
The three new complexes Tp(Py)Ln(CH3CO2)2(H2O) (Ln = Eu (1), Gd(2), or Tb (3)) were prepared and characterized… 
2015
2015
Diazoalkane complexes of ruthenium with tris(pyrazolyl)borate and bis(pyrazolyl)acetate ligands.
Diazoalkane complexes [Ru(Tp)(N2CAr1Ar2)(PPh3)L]BPh4 ( and ) [Tp = tris(pyrazolyl)borate; L = P(OMe)3, P(OEt)3; Ar1 = Ar2 = Ph… 
2008
2008
ScorpoPhos: a novel phosphine-nitrogen ligand containing a tris(pyrazolyl)borate ligand core.
A new tris(pyrazolyl)borate ligand bearing phosphine donor groups appended to the 3-position of the pyrazolyl rings is reported… 
2007
2007
Labeling of the neuropeptide enkephalin with functionalized tris(pyrazolyl)borate complexes: solid-phase synthesis and characterization of p-[Enk-OH]COC6H4TpPtMe3 and p-[Enk-OH]COC6H4TpMeRe(CO)3.
Bioconjugates of the neuropeptide Enkephalin (Enk = -Tyr-Gly-Gly-Phe-Leu-) labeled with organotransition metal tris… 
2005
2005
Unusual reactivity of tris(pyrazolyl)borate zirconium benzyl complexes.
The synthesis and reactivity of [Tp*Zr(CH2Ph)2][B(C6F5)4] (2, Tp* = HB(3,5-Me2pz)3, pz = pyrazolyl) have been explored to probe… 
2005
2005
Zinc-thiolate complexes of the bis(pyrazolyl)(thioimidazolyl)hydroborate tripods for the modeling of thiolate alkylating enzymes.
The new tripod ligands bis(pyrazolyl)(3-tert-butyl-2-thioimidazol-1-yl)hydroborate (L(1)) and bis(pyrazolyl)(3-isopropyl-2… 
2004
2004
Structural analysis of the conformational flexibility of tris(pyrazolyl)borate ligands and their analogues.
Database analysis and molecular mechanics were used to determine the conformational flexibility of tridentate scorpionate ligands… 
Highly Cited
1997
Highly Cited
1997
Synthesis and Characterization of the Benzoylformato Ferrous Complexes with the Hindered Tris(pyrazolyl)borate Ligand as a Structural Model for Mononuclear Non-Heme Iron Enzymes.
By using a hindered tripodal ligand, hydrotris(3-tert-butyl-5-isopropylpyrazol-1-yl)borate HB(3-tBu-5-iPrpz)(3), a series of… 
1997
1997
Hydrotris(pyrazolyl)borato Cycloocta-1,5-diene Complexes of Iridium(I): Synthetic Studies and Equilibria in Solution. X-ray Crystal Structures of a Four- and a Five-Coordinate Iridium(I) Hydrotris…
The compounds [Tp(3R,4R,5R)Ir(COD)] (COD = cycloocta-1,5-diene; Tp(3R,4R,5R) = hydrotris(pyrazolyl)borate (1), hydrotris(3… 
1996
1996
Syntheses of Cationic, Six-Coordinate Cadmium(II) Complexes Containing Tris(pyrazolyl)methane Ligands. Influence of Charge on Cadmium-113 NMR Chemical Shifts.
Treating a thf (thf = tetrahydrofuran) suspension of Cd(acac)(2) (acac = acetylacetonate) with 2 equiv of HBF(4).Et(2)O results… 
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