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tris(phosphino)borane

 
National Institutes of Health

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2 relations

Broader (2)

BoranesPhosphines

Papers overview

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Highly Cited
2012
Highly Cited
2012
Dihydrogen binding to isostructural S = ½ and S = 0 cobalt complexes.
Two isostructural, nonclassical Co(H(2)) complexes are prepared from their Co(N(2)) precursors using tris(phosphino)silyl and… Expand
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Highly Cited
2011
Highly Cited
2011
Terminal iron dinitrogen and iron imide complexes supported by a tris(phosphino)borane ligand.
Adaptable metallaboratranes: A tris- (phosphino)borane ligand stabilizes both low-valent Fe-N_2 complexes and a mid-valent imido… Expand
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2011
2011
Synthesis and reactivity of novel iron complexes supported by neutral tris(phosphino)borane ligands
Of central importance to elucidating iron's role in biol. nitrogen fixation are the accessible geometries and oxidn. states of… Expand
2011
2011
Iron complexes of a tris(phosphino)borane ligand as nitrogenase models
Biol. dinitrogen fixation - i.e. The redn. of N_2 to two equiv. of ammonia by addn. of protons and electrons - is thought to… Expand
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