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tris(1-pyrazolyl)methane

Known as: tpm cpd 
 
National Institutes of Health

Topic mentions per year

Topic mentions per year

2000-2017
01220002017

Related topics

Related topics

3 relations

Broader (2)

MethanePyrazoles
analogs & derivatives

Related mentions per year

Related mentions per year

1936-2018
19401960198020002020
tris(1-pyrazolyl)methane
Methane
Pyrazoles
analogs & derivatives

Papers overview

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2014
2014
Synthesis, structures, and optical properties of ruthenium(II) complexes of the tris(1-pyrazolyl)methane ligand.
Four new complex salts [Ru(II)Cl(Tpm)(L(A))2][PF6]n [Tpm = tris(1-pyrazolyl)methane; n = 1, L(A) = pyridine (py) 1 or ethyl… (More)
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2014
2014
Influence of the electronic configuration in the properties of d6-d5 mixed-valence complexes.
We report here the spectroscopic properties of four very closely related mixed-valence cyanide-bridged bimetallic complexes… (More)
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2013
2013
Electronic structure and catalytic aspects of [Ru(tpm)(bqdi)(Cl/H2O)]n, tpm = tris(1-pyrazolyl)methane and bqdi = o-benzoquinonediimine.
The diamagnetic complexes [Ru(tpm)(bqdi)(Cl)]ClO(4) ([1]ClO(4)) (tpm = tris(1-pyrazolyl)methane, bqdi = o-benzoquinonediimine… (More)
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2012
2012
Efficient energy transfer via the cyanide bridge in dinuclear complexes containing Ru(II) polypyridine moieties.
We report the synthesis, structure and properties of the cyanide-bridged dinuclear complex ions [Ru(L)(bpy)(μ-NC)M(CN)(5)](2… (More)
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2010
2010
Catalysis of mononuclear aquaruthenium complexes in oxygen evolution from water: a new radical coupling path using hydroxocerium(IV) species.
The mechanism of O(2) evolution from water catalyzed by a series of mononuclear aquaruthenium complexes, [Ru(terpy)(bpy)(OH(2… (More)
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2009
2009
Mononuclear metallacyclic silver(I) complexes of third generation bis(1-pyrazolyl)methane ligands.
The third-generation bis(1-pyrazolyl)methane ligands p-C(6)H(4)[CH(2)OCH(2)CH(pz)(2)](2) (L(p), pz = pyrazolyl ring) and m-C(6)H… (More)
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2007
2007
Electrochemical and photophysical properties of DNA metallo-intercalators containing the ruthenium(II) tris(1-pyrazolyl)methane unit.
Three new ruthenium(II) complexes containing the tris(1-pyrazolyl)methane (tpm) ligand have been prepared: [Ru(tpm)(L)(dppn)]n… (More)
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2007
2007
Structural comparisons of silver(I) complexes of third-generation ligands built from tridentate (o-C(6)H(4)[CH(2)OCH(2)C(pz)(3)](2)) versus bidentate poly(1-pyrazolyl)methane units (o-C(6)H(4)[CH(2…
The new bitopic, bis(1-pyrazolyl)methane-based ligand o-C6H4[CH2OCH2CH(pz)2]2 (L2, pz = pyrazolyl ring) is prepared from the… (More)
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2006
2006
New ruthenium nitrosyl complexes with tris(1-pyrazolyl)methane (tpm) and 2,2'-bipyridine (bpy) coligands. Structure, spectroscopy, and electrophilic and nucleophilic reactivities of bound nitrosyl.
The new compound [Ru(bpy)(tpm)NO](ClO4)3 [tpm = tris(1-pyrazolyl)methane; bpy = 2,2'-bipyridine] has been prepared in a stepwise… (More)
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2001
2001
Reversible osmium(VI) nitrido to osmium(II) ammine interconversion in complexes containing polypyrazolyl ligands.
This paper describes the 4e-/3H+ interconversion between NH3 and N3-, which is reversible in the coordination spheres of Os… (More)
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