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trimethylsilyldiazomethane

Known as: Silane, (diazomethyl)trimethyl-, TMSCHN2 
National Institutes of Health

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3 relations

Broader (2)

DiazomethaneTrimethylsilyl Compounds
analogs & derivatives

Papers overview

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2017
2017
Transition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane.
The transition metal free catalytic hydroboration of aldehydes and ketones is very limited and has not been reported with a well… 
2010
2010
Ruthenium-catalyzed synthesis of functional conjugated dienes via addition of two carbene units to alkynes.
The reaction of a variety of alkynes with N(2)CHSiMe(3), in the presence of Cp*RuCl(cod) as the catalyst precursor, leads to the… 
2010
2010
Trimethylsilyldiazomethane as a versatile stitching agent for the introduction of aziridines into functionalized organic molecules.
A highly enantioselective route for the introduction of aziridines into functionalized organic molecules was developed via a… 
2009
2009
A new benzoxepin metabolite isolated from endophytic fungus Phomopsis sp.
2007
2007
SILANE CROSSLINKING OF POLYETHYLENE: THE EFFECTS OF EVA, ATH AND SB2O3 ON PROPERTIES OF THE PRODUCTION IN CONTINUOUS GRAFTING OF LDPE
In this study, thermal, mechanical and fire retardant properties of silane-crosslinked low-density polyethylene (XLPE) containing… 
2007
2007
1,3-dipolar cycloadditions of trimethylsilyldiazomethane revisited: steric demand of the dipolarophile and the influence on product distribution.
The 1,3-dipolar cycloaddition of trimethylsilyldiazomethane with alpha,beta-unsaturated esters was examined. The resulting 1… 
Highly Cited
2006
Highly Cited
2006
Gold-catalyzed intramolecular allylation of silyl alkynes induced by silane alcoholysis.
The activation of alkynyl allyl silanes with a cationic gold catalyst in the presence of alcohols provides vinyl silanes that… 
Highly Cited
2002
Highly Cited
2002
Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C-silylaziridines--a cornucopia of…
Treatment of a range of N-sulfonyl (Ts and SES) imines derived from aromatic, heteroaromatic, aliphatic, and unsaturated… 
2000
2000
Highly selective aziridination of imines using trimethylsilyldiazomethane and applications of C-silylaziridines in synthesis
Trimethylsilyldiazomethane has been found to add directly to N-sulfonyl (Ts and SES) imines to afford aziridines in good yields… 
1994
1994
Simultaneous determination of granisetron and 7-hydroxygranisetron in human plasma by high-performance liquid chromatography with fluorescence detection.
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