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trimethylsilyldiazomethane

Known as: Silane, (diazomethyl)trimethyl-, TMSCHN2 
National Institutes of Health

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3 relations

Broader (2)

DiazomethaneTrimethylsilyl Compounds
analogs & derivatives

Papers overview

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2017
2017
Transition metal free catalytic hydroboration of aldehydes and aldimines by amidinato silane.
The transition metal free catalytic hydroboration of aldehydes and ketones is very limited and has not been reported with a well… 
2015
2015
On-cartridge derivatization coupled with solid-phase extraction for the ultra-sensitive determination of minodronic acid in human plasma by LC-MS/MS method.
2010
2010
Ruthenium-catalyzed synthesis of functional conjugated dienes via addition of two carbene units to alkynes.
The reaction of a variety of alkynes with N(2)CHSiMe(3), in the presence of Cp*RuCl(cod) as the catalyst precursor, leads to the… 
2007
2007
1,3-dipolar cycloadditions of trimethylsilyldiazomethane revisited: steric demand of the dipolarophile and the influence on product distribution.
The 1,3-dipolar cycloaddition of trimethylsilyldiazomethane with alpha,beta-unsaturated esters was examined. The resulting 1… 
Highly Cited
2006
Highly Cited
2006
Gold-catalyzed intramolecular allylation of silyl alkynes induced by silane alcoholysis.
The activation of alkynyl allyl silanes with a cationic gold catalyst in the presence of alcohols provides vinyl silanes that… 
2006
2006
Interference from a glucuronide metabolite in the determination of ramipril and ramiprilat in human plasma and urine by gas chromatography-mass spectrometry.
2005
2005
Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynylboronates.
The ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynes developed by Dixneuf and co-workers was applied… 
Highly Cited
2002
Highly Cited
2002
Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C-silylaziridines--a cornucopia of…
Treatment of a range of N-sulfonyl (Ts and SES) imines derived from aromatic, heteroaromatic, aliphatic, and unsaturated… 
2000
2000
Highly selective aziridination of imines using trimethylsilyldiazomethane and applications of C-silylaziridines in synthesis
Trimethylsilyldiazomethane has been found to add directly to N-sulfonyl (Ts and SES) imines to afford aziridines in good yields… 
1994
1994
Simultaneous determination of granisetron and 7-hydroxygranisetron in human plasma by high-performance liquid chromatography with fluorescence detection.
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