V. Aggarwal

Publications760
h-index72
Citations17,619
Highly Influential Citations53
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In the Solid Phase
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Science of Synthesis
“Science of Synthesis is an indispensable tome of chemical information organized in an intuitive and logical way. It contains information on nearly every aspect of chemical reactivity and, for me, is…
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Enantiodivergent conversion of chiral secondary alcohols into tertiary alcohols
TLDR
A broad range of tertiary alcohols can now be easily made by this method with very high levels of selectivity, and it is expected that this methodology could find widespread application, as the intermediate tertiary boronic esters can potentially be converted into a range of functional groups with retention of configuration.
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Mechanism of the Morita-Baylis-Hillman reaction: a computational investigation.
TLDR
The mechanism of the MBH reaction is addressed, focusing on the reaction between methyl acrylate and benzaldehyde, catalyzed by a tertiary amine, and it is predicted that deprotonation of the alpha-position is the rate-determining step and occurs through a cyclic transition state.
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Reevaluation of the mechanism of the Baylis-Hillman reaction: implications for asymmetric catalysis.
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Comprehensive Organic Synthesis II
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Enantioselective Organocatalysis: Reactions and Experimental Procedures
Unexpected Side Reactions of Imidazolium-Based Ionic Liquids in the Base-Catalyzed Baylis—Hillman Reaction.
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Asymmetric Ylide Reactions: Epoxidation, Cyclopropanation, Aziridination, Olefination, and Rearrangement.
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The use of vinyl sulfonium salts in the stereocontrolled asymmetric synthesis of epoxide- and aziridine-fused heterocycles: application to the synthesis of (-)-balanol.
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