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Thesis is structured in three different parts. The first part is dedicated to the total synthesis of the Z -isomers of nonenolide… Expand Starting from the conveniently available ex-chiral pool building block (R,R)-hexa-1,5-diene-3,4-diol, the ten-membered ring… Expand A highly convergent, stereoselective total synthesis of a ten-memberedlactone, stagonolide G, is described. Epoxide ring-opening… Expand A convergent synthesis of the structure proposed for the naturally occurring lactone stagonolide G is described. All three… Expand The first total synthesis of 9-membered macrolide, stagonolide-F (3), starting from commercially available 1,5-pentane diol is… Expand Stagonospora cirsii, a fungal pathogen isolated from Cirsium arvense and proposed as a potential mycoherbicide of this perennial… Expand Stagonospora cirsii Davis, a fungal pathogen isolated from Cirsium arvense (commonly called Canada thistle) and proposed as a… Expand A structure-activity relationships study was conducted assaying 15 natural analogues and derivatives belonging to two groups of… Expand Stagonospora cirsii is a pathogen of Cirsium arvense, causing necrotic lesions on leaves of this noxious weed. The fungus… Expand