semipinacol
National Institutes of Health
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Two photo-catalytic tandem alkyl radical addition/semipinacol rearrangement reactions of cycloalkanol-substituted styrenes with N…
Over the past few decades, the semipinacol rearrangement has been widely applied in the field of organic synthesis. However, its…
A novel propargylic electrophile-induced tandem intermolecular addition-semipinacol rearrangement was developed efficiently under…
A novel halogenation/semipinacol rearrangement of α-diazo alcohol catalyzed by Lewis base has been developed through a carbene…
The synthesis of 2,3-disubstituted pyrroles via TMSOTf-assisted cyclization reaction of 3,5,5-trimethyl-2,3-epoxycyclohexan-1…
( )-Cephalotaxine 1 was first isolated from Cephalotaxus drupacea and C. fortunei as a major alkaloid among a series of its ester…
A TiCl(4)-promoted domino semipinacol-Schmidt reaction of oxaspiropentane-azide provides an easy access to bridged azatricyclic…
Highly Enantioselective Hydrogenation of Styrenes Directed by 2 ¢ -Hydroxyl Groups
A palladium-catalyzed tandem semipinacol rearrangement/direct arylation reaction using α-aryl isopropenyl-tert-cyclobutanols has…
A novel and highly diastereoselective samarium-catalyzed tandem rearrangement/reduction of secondary alpha-hydroxy epoxides…