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samarium diiodide

Known as: SmI(2) 
National Institutes of Health

Papers overview

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Highly Cited
2012
Highly Cited
2012
Reactions proceeding through open-shell, single-electron pathways offer attractive alternative outcomes to those proceeding… 
Highly Cited
2010
Highly Cited
2010
Mechanistic studies show the importance of iodide displacement by additives that accelerate reactions of samarium diiodide. The… 
2010
2010
The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of… 
Review
2009
Review
2009
Introduced by Henri Kagan more than three decades ago, samarium diiodide (SmI(2)) has found increasing application in chemical… 
Highly Cited
2008
Highly Cited
2008
The mechanistic importance of HMPA and proton donors (methanol, 2-methyl-2-propanol, and 2,2,2-trifluoroethanol) on SmI2… 
Highly Cited
2007
Highly Cited
2007
The asymmetric catalytic aziridination reaction (AZ reaction) of N-dianisylmethylimines (N-DAM-imines) with ethyl diazoacetate is… 
Review
2006
Review
2006
In this perspective, an overview of our experiences on the application of samarium diiodide in organic synthesis for the… 
2000
2000
Samarium(II) iodide has been employed to promote vinylogous pinacol coupling reaction of aldehyde onto alpha,beta-unsaturated… 
1999
1999
Beware of samarium diiodide and aryl ketones! If the ketyl radical anion which is formed by electron transfer finds a properly… 
Highly Cited
1996
Highly Cited
1996
The authors examined the ability of samarium diiodide to promote N-O cleavage in N-acylated O-alkylhydroxylamines. The reaction…