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samarium diiodide

Known as: SmI(2) 
National Institutes of Health

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2 relations

Broader (2)

IodidesSamarium

Papers overview

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2010
2010
Tripyrrolidinophosphoric acid triamide as an activator in samarium diiodide reductions.
The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of… 
2009
2009
Highly diastereoselective samarium diiodide induced cyclizations of new 3-substituted indole derivatives.
Herein, we describe the synthesis of new functionalized tricyclic and tetracyclic indole derivatives via samarium diiodide… 
Highly Cited
2007
Highly Cited
2007
Direct access to N-H-aziridines from asymmetric catalytic aziridination with borate catalysts derived from vaulted binaphthol and vaulted biphenanthrol ligands.
The asymmetric catalytic aziridination reaction (AZ reaction) of N-dianisylmethylimines (N-DAM-imines) with ethyl diazoacetate is… 
Review
2006
Review
2006
Creating carbon-carbon bonds with samarium diiodide for the synthesis of modified amino acids and peptides.
In this perspective, an overview of our experiences on the application of samarium diiodide in organic synthesis for the… 
2005
2005
Asymmetric conjugate reductions with samarium diiodide: asymmetric synthesis of (2S,3R)- and (2S,3S)-[2-2H,3-2H]-leucine-(S)-phenylalanine dipeptides and (2S,3R)-[2-(2)H,3-2H]-phenylalanine methyl…
The highly diastereoselective samarium diiodide and D(2)O-promoted conjugate reduction of homochiral (E)- and (Z)-benzylidene and… 
2004
2004
Diastereoselective conjugate reduction with samarium diiodide: asymmetric synthesis of methyl (2S,3R)-N-acetyl-2-amino-2,3-dideuterio-3-phenylpropionate.
A highly diastereoselective conjugate reduction using SmI2 and D2O has been demonstrated on a homochiral benzylidene… 
2001
2001
Sequential elimination-reduction reactions promoted by samarium diiodide: synthesis of 2,3-dideuterioesters or -amides.
A facile and general sequential elimination/reduction process promoted by samarium diiodide provides an efficient method for… 
2001
2001
Synthesis of ferrocenyl alkenes, dienes, and enynes via samarium diiodide promoted tandem addition and dehydration of ferrocenyl carbonyls with halides.
A practical method for preparation of ferrocenyl alkenes, dienes, and enynes from ferrocenyl carbonyls was explored. A one-pot… 
2000
2000
Cyclization into hydrindanones using samarium diiodide
Samarium(II) iodide has been employed to promote vinylogous pinacol coupling reaction of aldehyde onto alpha,beta-unsaturated… 
1999
1999
A New Samarium Diiodide Induced Reaction: Intramolecular Attack of Ketyl Radical Anions on Aryl Substituents with Formation of 1,4-Cyclohexadiene Derivatives.
Beware of samarium diiodide and aryl ketones! If the ketyl radical anion which is formed by electron transfer finds a properly… 
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