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rosmarinecine

National Institutes of Health

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Pyrrolizidine Alkaloids

Papers overview

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2013
2013
Ti(III)-mediated radical cyclization of epoxy-β-aminoacrylate in the synthesis of the substituted pyrrolidine core of necine bases: synthesis of 2-epi-rosmarinecine
A radical-mediated approach to the necine base 2-epi-rosmarinecine is described. The synthesis is based on the stereoselective… 
2006
2006
One-pot synthesis of cyclic nitrones and their conversion to pyrrolizidines: 7a-epi-crotanecine inhibits alpha-mannosidases.
[reaction: see text] A new straightforward and inexpensive one-pot procedure is described for the preparation of enantiopure five… 
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