phorboxazole B
National Institutes of Health
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The synthesis of the C1-C19 bis-pyran unit of phorboxazole B has been achieved. The key pyran rings were constructed by means of…
An efficient and highly convergent total synthesis of the potent antitumor agent phorboxazole B has been achieved. The synthetic…
[reaction: see text]. Three segment-coupling Prins approaches to the C3-C19 segment of phorboxazole B have been developed. One…
The convergent syntheses of the C(1-32) and C(33-46) domains of phorboxazole B are described. An iterative cyclocondensation…
An efficient synthesis of the C20-C46 segment of phorboxazole B is described. The key steps involved Hg(OAc)(2)/I(2)-induced…
An efficient synthesis of the C20-C46 segment of phorboxazole B is described. The key steps involved Hg(OAc)(2)/I-2-induced…
A steroselective synthesis of C28-C46 segment of phorboxazole B is described. Key features of the synthetic route involved the…
A convergent and enantioselective synthesis of the C13-C19 bis-oxane oxazole fragment of phorboxazole B has been described. This…
The synthesis of phorboxazole B has been accomplished in 27 linear steps and an overall yield of 12.6%. The absolute…