perophoramidine
National Institutes of Health
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Easily accessible 3,3′-diindolylmethanes (DIMs) were utilized to generate a focused library of indolo[2,3-b]quinolines (2…
The first copper-catalyzed intermolecular asymmetric propargylic dearomatization/annulation cascade sequence of indoles via a…
The communesin alkaloids are a diverse family of Penicillium-derived alkaloids. Their caged-polycyclic structure and intriguing…
We describe a catalytic asymmetric total synthesis of the ascidian alkaloid (–)-perophoramidine employing a Mo-catalyzed…
Expedient synthetic approaches to the highly functionalized polycyclic alkaloids communesin F and perophoramidine are described…
An efficient, unified, and stereodivergent approach toward communesin F and perophoramidine was examined. The C(3) all-carbon…
A concise approach toward the total synthesis of the communesin alkaloids and perophoramidine is reported. The strategy relies on…
The communesin/nomofungin/perophoramidine story is an impressive example of how biogenetic considerations can lead to the…
The first total synthesis of racemic perophoramidine is described. The key step features the highly stereoselective introduction…
A halogen-selective tandem intramolecular Heck/carbonylation reaction has been developed for the construction of the C,E,F-ring…