miyakolide
National Institutes of Health
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A transition metal-mediated, atom-economical approach toward the crucial A and D rings of miyakolide is described. A Pd-catalyzed…
The first total synthesis of the marine macrolide miyakolide has been achieved, and its absolute stereochemistry has been…
Presented are the stereoselective syntheses of the A (C18-C28), B (C14-C17), C (C6-C13), D (Cl-C5), C'D' (C1-C13) fragments and…