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iron corrole

 
National Institutes of Health

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Metalloporphyrins

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2014
2014
A cytotoxic and cytostatic gold(III) corrole.
We have synthesized and characterized a water-soluble gold(III) corrole (1-Au) that is highly toxic to cisplatin-resistant cancer… Expand
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2012
2012
The structural chemistry of metallocorroles: combined X-ray crystallography and quantum chemistry studies afford unique insights.
Although they share some superficial structural similarities with porphyrins, corroles, trianionic ligands with contracted cores… Expand
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2012
2012
Picosecond and femtosecond optical nonlinearities of novel corroles
We present our results from the experimental and modeling studies of picosecond (ps) and femtosecond (fs) nonlinearities of two… Expand
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2012
2012
Photophysical properties and singlet oxygen generation of three sets of halogenated corroles.
The luminescence, excited-state absorption, and singlet oxygen generation measurements were performed on three kinds of… Expand
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2011
2011
Gold(I) and gold(III) corroles.
Corrole complexes with gold(I) and gold(III) were synthesized and their structural, photophysical, and electrochemical properties… Expand
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2009
2009
Copper corroles are inherently saddled.
X-ray crystallographic analyses of two sterically unhindered copper meso-triarylcorroles, Cu[5,15-P(2)-10-(4-MeOP)C] and Cu[5,15… Expand
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2009
2009
Demetalation of silver(III) corrolates.
Several procedures for the demetalation of silver(III) corrolates have been tested. Acidic conditions induce removal of the… Expand
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2009
2009
Production of a putative iron(V)-oxocorrole species by photo-disproportionation of a bis-corrole-diiron(IV)-mu-oxo dimer: implication for a green oxidation catalyst.
Photodisproportionation of a bis-corrole-diiron(IV)-mu-oxo dimer gave a corrole-iron(III) species and a corrole-iron(V)-oxo… Expand
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2006
2006
Synthesis and full characterization of molybdenum and antimony corroles and utilization of the latter complexes as very efficient catalysts for highly selective aerobic oxygenation reactions.
Two molybdenum and three antimony corroles were isolated and characterized by NMR, EPR, and electrochemistry. The very negative… Expand
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2003
2003
First synthesis of perfluorinated corrole and its mn=o complex.
A novel perfluorinated corrole, 2,3,7,8,12,13,17,18-octafluoro-5,10,15-tris(pentafluorophenyl)corrole, and its manganese(III) and… Expand
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