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hemicalide

National Institutes of Health

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Polyketides

Papers overview

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2019
2019
Assembly of the Entire Carbon Backbone of a Stereoisomer of the Antitumor Marine Natural Product Hemicalide.
A strategy for the assembly of the entire carbon backbone of a stereoisomer of the antitumor marine natural product hemicalide… 
2016
2016
Toward the stereochemical assignment and synthesis of hemicalide: DP4f GIAO-NMR analysis and synthesis of a reassigned C16-C28 subunit.
Using the DP4f GIAO-NMR method, the stereochemistry of hemicalide was computationally analysed, resulting in a reassignment at… 
2016
2016
Elaboration of Sterically Hindered δ-Lactones through Ring-Closing Metathesis: Application to the Synthesis of the C1-C27 Fragment of Hemicalide.
The synthesis of the C1-C27 fragment of hemicalide, a marine metabolite displaying a unique potent antiproliferative activity… 
2015
2015
Synthetic Studies toward the C32-C46 Segment of Hemicalide. Assignment of the Relative Configuration of the C36-C42 Subunit.
The synthesis of five diastereomeric model compounds incorporating the C32-C46 segment of the antitumor marine natural product… 
2013
2013
Relative stereochemical determination and synthesis of the C17-C25 δ-lactone fragment of hemicalide.
Hemicalide is a novel marine metabolite polyketide distinguished by a unique mechanism of action. Because of insufficient… 
2013
2013
Synthetic studies on hemicalide: development of a convergent approach toward the C1-C25 fragment.
Synthetic studies on hemicalide, a recently isolated marine natural product displaying highly potent antiproliferative activity… 
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