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fumitremorgin B

National Institutes of Health

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2019
2019
On the reaction mechanism of an endoperoxide ring formation by fumitremorgin B endoperoxidase. The right arrangement makes a difference.
Fumitremorgin B endoperoxidase (FtmF) belongs to 2-oxoglutarate dependent dioxygenases and catalyzes an unusual oxidative… 
2018
2018
Asymmetric abstraction of two chemically-equivalent methylene hydrogens: significant enantioselectivity of endoperoxide presented by fumitremorgin B endoperoxidase.
The combination of the inert C-H bond activation and asymmetric synthesis, especially the transformation of prochiral sp3… 
2017
2017
Insights into the unprecedented epoxidation mechanism of fumitremorgin B endoperoxidase (FtmOx1) from Aspergillus fumigatus by QM/MM calculations.
Fumitremorgin B endoperoxidase (FtmOx1) from Aspergillus fumigatus is the first reported α-ketoglutarate-dependent mononuclear… 
2014
2014
A Proteomic Approach to Investigating Gene Cluster Expression and Secondary Metabolite Functionality in Aspergillus fumigatus
A combined proteomics and metabolomics approach was utilised to advance the identification and characterisation of secondary… 
2013
2013
Isolation and biological evaluation of secondary metabolites of the endophytic fungus Aspergillus fumigatus from Astragalus membranaceus
Highly Cited
2013
Highly Cited
2013
Induction of diverse secondary metabolites in Aspergillus fumigatus by microbial co-culture
An established culture of Aspergillus fumigatus MBC-F1-10 proved to be very receptive to external stimuli and reacted with the… 
2012
2012
Identification of the Verruculogen Prenyltransferase FtmPT3 by a Combination of Chemical, Bioinformatic and Biochemical Approaches
Previous studies showed that verruculogen is the end product of a biosynthetic gene cluster for fumitremorgin‐type alkaloids in… 
Highly Cited
2009
Highly Cited
2009
FtmOx1, a non-heme Fe(II) and alpha-ketoglutarate-dependent dioxygenase, catalyses the endoperoxide formation of verruculogen in Aspergillus fumigatus.
Verruculogen is a tremorgenic mycotoxin and contains an endoperoxide bond. In this study, we describe the cloning, overexpression… 
1996
1996
The isolation, purification and identification of fumitremorgin B produced by Aspergillus fumigatus.
Twenty-six strains of Aspergillus fumigatus were screened for toxigenicity for fumitremorgins A and B. Twenty-three of 26 strains… 
1983
1983
An intermediary role for the tremorgenic mycotoxin TR-2 in the biosynthesis of verruculogen.
14C-Labelled compound TR-2, a tremorgenic mycotoxin, was administered to Penicillium raistrickii in submerged fermentation. Half… 
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