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fumitremorgin B

National Institutes of Health

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2019
2019
On the reaction mechanism of an endoperoxide ring formation by fumitremorgin B endoperoxidase. The right arrangement makes a difference.
Fumitremorgin B endoperoxidase (FtmF) belongs to 2-oxoglutarate dependent dioxygenases and catalyzes an unusual oxidative… 
2018
2018
Asymmetric abstraction of two chemically-equivalent methylene hydrogens: significant enantioselectivity of endoperoxide presented by fumitremorgin B endoperoxidase.
The combination of the inert C-H bond activation and asymmetric synthesis, especially the transformation of prochiral sp3… 
2018
2018
A Nonheme FeII/2-Oxoglutarate-Dependent Oxygenase Catalyzes a Double Bond Migration within a Dimethylallyl Moiety Accompanied by Hydroxylation.
Prenylation of cyclodipeptides contributes largely to the structure diversification and biological activity. The prenylated… 
2017
2017
Insights into the unprecedented epoxidation mechanism of fumitremorgin B endoperoxidase (FtmOx1) from Aspergillus fumigatus by QM/MM calculations.
Fumitremorgin B endoperoxidase (FtmOx1) from Aspergillus fumigatus is the first reported α-ketoglutarate-dependent mononuclear… 
2013
2013
Isolation and biological evaluation of secondary metabolites of the endophytic fungus Aspergillus fumigatus from Astragalus membranaceus
2012
2012
Identification of the Verruculogen Prenyltransferase FtmPT3 by a Combination of Chemical, Bioinformatic and Biochemical Approaches
Previous studies showed that verruculogen is the end product of a biosynthetic gene cluster for fumitremorgin‐type alkaloids in… 
Highly Cited
2009
Highly Cited
2009
FtmOx1, a non-heme Fe(II) and alpha-ketoglutarate-dependent dioxygenase, catalyses the endoperoxide formation of verruculogen in Aspergillus fumigatus.
Verruculogen is a tremorgenic mycotoxin and contains an endoperoxide bond. In this study, we describe the cloning, overexpression… 
1996
1996
The isolation, purification and identification of fumitremorgin B produced by Aspergillus fumigatus.
Twenty-six strains of Aspergillus fumigatus were screened for toxigenicity for fumitremorgins A and B. Twenty-three of 26 strains… 
1996
1996
The Preparation and Identification of Fumitremorgin B—Hemisuccinate—Carrier Proteins
A method for the preparation and identification of fumitremorgin B-hemisuccinatecarrier protein is described.The overall yield of… 
1983
1983
An intermediary role for the tremorgenic mycotoxin TR-2 in the biosynthesis of verruculogen.
14C-Labelled compound TR-2, a tremorgenic mycotoxin, was administered to Penicillium raistrickii in submerged fermentation. Half… 
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